Matrix studies of the B̃2A2′→X̃ 2E″ transition of the sym-C6Cl3F 3+ radical cation

V. E. Bondybey

doi:10.1063/1.438815

Matrix studies of the B̃²A₂′→X̃ ²E″ transition of the sym-C₆Cl₃F ₃⁺ radical cation

V. E. Bondybey

Alcatel-Lucent

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The laser induced fluorescence spectra of the sym-C₆Cl ₃F₃⁺ radical cation were observed and analyzed. The cations are generated in rare gas matrices by VUV photoionization of the parent halobenzene. They fluoresce in solid Ne and Ar with near unity quantum efficiency and exhibit a well resolved vibronic structure. A radiative lifetime of 29±5 nsec is found for the emission in Ne host. Both the totally symmetric a₁ and degenerate e′ modes are active in the spectrum. Analysis of the ground state vibrational structure yields the Jahn-Teller distortion parameters for several e′ vibration modes.

Original language	English
Pages (from-to)	3586-3591
Number of pages	6
Journal	Journal of Chemical Physics
Volume	71
Issue number	9
DOIs	https://doi.org/10.1063/1.438815
State	Published - 1979
Externally published	Yes

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title = "Matrix studies of the {\~B}2A2′→{\~X} 2E″ transition of the sym-C6Cl3F 3+ radical cation",

abstract = "The laser induced fluorescence spectra of the sym-C6Cl 3F3+ radical cation were observed and analyzed. The cations are generated in rare gas matrices by VUV photoionization of the parent halobenzene. They fluoresce in solid Ne and Ar with near unity quantum efficiency and exhibit a well resolved vibronic structure. A radiative lifetime of 29±5 nsec is found for the emission in Ne host. Both the totally symmetric a1 and degenerate e′ modes are active in the spectrum. Analysis of the ground state vibrational structure yields the Jahn-Teller distortion parameters for several e′ vibration modes.",

author = "Bondybey, \{V. E.\}",

year = "1979",

doi = "10.1063/1.438815",

language = "English",

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pages = "3586--3591",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

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T1 - Matrix studies of the B̃2A2′→X̃ 2E″ transition of the sym-C6Cl3F 3+ radical cation

AU - Bondybey, V. E.

PY - 1979

Y1 - 1979

N2 - The laser induced fluorescence spectra of the sym-C6Cl 3F3+ radical cation were observed and analyzed. The cations are generated in rare gas matrices by VUV photoionization of the parent halobenzene. They fluoresce in solid Ne and Ar with near unity quantum efficiency and exhibit a well resolved vibronic structure. A radiative lifetime of 29±5 nsec is found for the emission in Ne host. Both the totally symmetric a1 and degenerate e′ modes are active in the spectrum. Analysis of the ground state vibrational structure yields the Jahn-Teller distortion parameters for several e′ vibration modes.

AB - The laser induced fluorescence spectra of the sym-C6Cl 3F3+ radical cation were observed and analyzed. The cations are generated in rare gas matrices by VUV photoionization of the parent halobenzene. They fluoresce in solid Ne and Ar with near unity quantum efficiency and exhibit a well resolved vibronic structure. A radiative lifetime of 29±5 nsec is found for the emission in Ne host. Both the totally symmetric a1 and degenerate e′ modes are active in the spectrum. Analysis of the ground state vibrational structure yields the Jahn-Teller distortion parameters for several e′ vibration modes.

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U2 - 10.1063/1.438815

DO - 10.1063/1.438815

M3 - Article

AN - SCOPUS:0141932385

SN - 0021-9606

VL - 71

SP - 3586

EP - 3591

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 9

ER -

Matrix studies of the B̃²A₂′→X̃ ²E″ transition of the sym-C₆Cl₃F ₃⁺ radical cation

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