Matrix Laser Fluorescence Spectra of Several Fluorobenzene Radical Cations

V. E. Bondybey; T. A. Miller; J. H. English

doi:10.1021/ja00499a033

Matrix Laser Fluorescence Spectra of Several Fluorobenzene Radical Cations

V. E. Bondybey, T. A. Miller, J. H. English

Alcatel-Lucent

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26 Scopus citations

Abstract

Several fluorobenzene radical cations were generated by vacuum UV photolysis of the parent fluorobenzenes in solid Ar matrix, and their laser fluorescence excitation spectra were studied. Their spectra show a well-resolved vibronic structure, which appears to be essentially unperturbed by the solid. Vibrational analysis provides strong evidence for the occurrence of a Jahn-Teiler distortion in the degenerate ²E_1g ground slate of C₆F₆⁺.

Original language	English
Pages (from-to)	1248-1253
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	101
Issue number	5
DOIs	https://doi.org/10.1021/ja00499a033
State	Published - 1 Feb 1979
Externally published	Yes

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title = "Matrix Laser Fluorescence Spectra of Several Fluorobenzene Radical Cations",

abstract = "Several fluorobenzene radical cations were generated by vacuum UV photolysis of the parent fluorobenzenes in solid Ar matrix, and their laser fluorescence excitation spectra were studied. Their spectra show a well-resolved vibronic structure, which appears to be essentially unperturbed by the solid. Vibrational analysis provides strong evidence for the occurrence of a Jahn-Teiler distortion in the degenerate 2E1g ground slate of C6F6+.",

author = "Bondybey, {V. E.} and Miller, {T. A.} and English, {J. H.}",

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AU - Miller, T. A.

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N2 - Several fluorobenzene radical cations were generated by vacuum UV photolysis of the parent fluorobenzenes in solid Ar matrix, and their laser fluorescence excitation spectra were studied. Their spectra show a well-resolved vibronic structure, which appears to be essentially unperturbed by the solid. Vibrational analysis provides strong evidence for the occurrence of a Jahn-Teiler distortion in the degenerate 2E1g ground slate of C6F6+.

AB - Several fluorobenzene radical cations were generated by vacuum UV photolysis of the parent fluorobenzenes in solid Ar matrix, and their laser fluorescence excitation spectra were studied. Their spectra show a well-resolved vibronic structure, which appears to be essentially unperturbed by the solid. Vibrational analysis provides strong evidence for the occurrence of a Jahn-Teiler distortion in the degenerate 2E1g ground slate of C6F6+.

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Matrix Laser Fluorescence Spectra of Several Fluorobenzene Radical Cations

Abstract

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