Mass Selected ZEKE-Spectra of FeC2-Anions: A Spectroscopic Access to Intermediates in Catalytic Reactions of Hydrocarbons on Metal Surfaces

G. Drechsler; C. Bäßmann; U. Boesl; E. W. Schlag

doi:10.1515/zna-1994-1228

Mass Selected ZEKE-Spectra of FeC₂-Anions: A Spectroscopic Access to Intermediates in Catalytic Reactions of Hydrocarbons on Metal Surfaces

G. Drechsler
, C. Bäßmann
, U. Boesl
, E. W. Schlag

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Zero-kinetic-energy (ZEKE) photoelectron spectra of metalcarbide anions are presented, allowing a high resolution spectroscopic access to intermediates in catalytic reactions of hydrocarbons on metal surfaces. As a first compound, FeC₂ (an intermediate of the iron/acetylene system) has been chosen. Important for successful ZEKE spectroscopy was a special anion source and the selection by time-of-flight mass spectrometry. In addition, conventional laser induced photo-detachment photoelectron spectroscopy in combination with our anion source and mass analyzer delivered valuable new information.

Original language	English
Pages (from-to)	1256-1258
Number of pages	3
Journal	Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume	49
Issue number	12
DOIs	https://doi.org/10.1515/zna-1994-1228
State	Published - 1 Dec 1994

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10.1515/zna-1994-1228

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title = "Mass Selected ZEKE-Spectra of FeC2-Anions: A Spectroscopic Access to Intermediates in Catalytic Reactions of Hydrocarbons on Metal Surfaces",

abstract = "Zero-kinetic-energy (ZEKE) photoelectron spectra of metalcarbide anions are presented, allowing a high resolution spectroscopic access to intermediates in catalytic reactions of hydrocarbons on metal surfaces. As a first compound, FeC2 (an intermediate of the iron/acetylene system) has been chosen. Important for successful ZEKE spectroscopy was a special anion source and the selection by time-of-flight mass spectrometry. In addition, conventional laser induced photo-detachment photoelectron spectroscopy in combination with our anion source and mass analyzer delivered valuable new information.",

author = "G. Drechsler and C. B{\"a}{\ss}mann and U. Boesl and Schlag, \{E. W.\}",

year = "1994",

month = dec,

day = "1",

doi = "10.1515/zna-1994-1228",

language = "English",

volume = "49",

pages = "1256--1258",

journal = "Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences",

issn = "0932-0784",

publisher = "Walter de Gruyter GmbH",

number = "12",

}

Mass Selected ZEKE-Spectra of FeC₂-Anions: A Spectroscopic Access to Intermediates in Catalytic Reactions of Hydrocarbons on Metal Surfaces. / Drechsler, G.; Bäßmann, C.; Boesl, U. et al.
In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Vol. 49, No. 12, 01.12.1994, p. 1256-1258.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Mass Selected ZEKE-Spectra of FeC2-Anions

T2 - A Spectroscopic Access to Intermediates in Catalytic Reactions of Hydrocarbons on Metal Surfaces

AU - Drechsler, G.

AU - Bäßmann, C.

AU - Boesl, U.

AU - Schlag, E. W.

PY - 1994/12/1

Y1 - 1994/12/1

N2 - Zero-kinetic-energy (ZEKE) photoelectron spectra of metalcarbide anions are presented, allowing a high resolution spectroscopic access to intermediates in catalytic reactions of hydrocarbons on metal surfaces. As a first compound, FeC2 (an intermediate of the iron/acetylene system) has been chosen. Important for successful ZEKE spectroscopy was a special anion source and the selection by time-of-flight mass spectrometry. In addition, conventional laser induced photo-detachment photoelectron spectroscopy in combination with our anion source and mass analyzer delivered valuable new information.

AB - Zero-kinetic-energy (ZEKE) photoelectron spectra of metalcarbide anions are presented, allowing a high resolution spectroscopic access to intermediates in catalytic reactions of hydrocarbons on metal surfaces. As a first compound, FeC2 (an intermediate of the iron/acetylene system) has been chosen. Important for successful ZEKE spectroscopy was a special anion source and the selection by time-of-flight mass spectrometry. In addition, conventional laser induced photo-detachment photoelectron spectroscopy in combination with our anion source and mass analyzer delivered valuable new information.

UR - https://www.scopus.com/pages/publications/21844484282

U2 - 10.1515/zna-1994-1228

DO - 10.1515/zna-1994-1228

M3 - Article

AN - SCOPUS:21844484282

SN - 0932-0784

VL - 49

SP - 1256

EP - 1258

JO - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences

JF - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences

IS - 12

ER -

Mass Selected ZEKE-Spectra of FeC₂-Anions: A Spectroscopic Access to Intermediates in Catalytic Reactions of Hydrocarbons on Metal Surfaces

Abstract

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