Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids

Oriol Jimenez; Thomas E. Müller; Carsten Sievers; Andreas Spirkl; Johannes A. Lercher

doi:10.1039/b605567b

Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids

Oriol Jimenez
, Thomas E. Müller
, Carsten Sievers
, Andreas Spirkl
, Johannes A. Lercher

Chair of Chemical Technology II

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts combining soft Lewis acidic and strong Brønsted acidic functions; the materials showed exceptional catalytic activity for the addition of aniline to styrene, providing the Markownikoff product under kinetically controlled conditions and mainly the anti-Markownikoff product in the thermodynamic regime.

Original language	English
Pages (from-to)	2974-2976
Number of pages	3
Journal	Chemical Communications
Issue number	28
DOIs	https://doi.org/10.1039/b605567b
State	Published - 2006

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title = "Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids",

abstract = "The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts combining soft Lewis acidic and strong Br{\o}nsted acidic functions; the materials showed exceptional catalytic activity for the addition of aniline to styrene, providing the Markownikoff product under kinetically controlled conditions and mainly the anti-Markownikoff product in the thermodynamic regime.",

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T1 - Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids

AU - Jimenez, Oriol

AU - Müller, Thomas E.

AU - Sievers, Carsten

AU - Spirkl, Andreas

AU - Lercher, Johannes A.

PY - 2006

Y1 - 2006

N2 - The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts combining soft Lewis acidic and strong Brønsted acidic functions; the materials showed exceptional catalytic activity for the addition of aniline to styrene, providing the Markownikoff product under kinetically controlled conditions and mainly the anti-Markownikoff product in the thermodynamic regime.

AB - The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts combining soft Lewis acidic and strong Brønsted acidic functions; the materials showed exceptional catalytic activity for the addition of aniline to styrene, providing the Markownikoff product under kinetically controlled conditions and mainly the anti-Markownikoff product in the thermodynamic regime.

UR - https://www.scopus.com/pages/publications/33745837101

U2 - 10.1039/b605567b

DO - 10.1039/b605567b

M3 - Article

AN - SCOPUS:33745837101

SN - 1359-7345

SP - 2974

EP - 2976

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids

Abstract

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