Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids

Oriol Jimenez; Thomas E. Müller; Carsten Sievers; Andreas Spirkl; Johannes A. Lercher

doi:10.1039/b605567b

Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids

Oriol Jimenez, Thomas E. Müller, Carsten Sievers, Andreas Spirkl, Johannes A. Lercher

Chair of Chemical Technology II

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts combining soft Lewis acidic and strong Brønsted acidic functions; the materials showed exceptional catalytic activity for the addition of aniline to styrene, providing the Markownikoff product under kinetically controlled conditions and mainly the anti-Markownikoff product in the thermodynamic regime.

Original language	English
Pages (from-to)	2974-2976
Number of pages	3
Journal	Chemical Communications
Issue number	28
DOIs	https://doi.org/10.1039/b605567b
State	Published - 2006

Access to Document

10.1039/b605567b

Cite this

@article{80f21ae03a9e49849a05d8db95c1a539,

title = "Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids",

abstract = "The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts combining soft Lewis acidic and strong Br{\o}nsted acidic functions; the materials showed exceptional catalytic activity for the addition of aniline to styrene, providing the Markownikoff product under kinetically controlled conditions and mainly the anti-Markownikoff product in the thermodynamic regime.",

author = "Oriol Jimenez and M{\"u}ller, {Thomas E.} and Carsten Sievers and Andreas Spirkl and Lercher, {Johannes A.}",

year = "2006",

doi = "10.1039/b605567b",

language = "English",

pages = "2974--2976",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "28",

}

TY - JOUR

T1 - Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids

AU - Jimenez, Oriol

AU - Müller, Thomas E.

AU - Sievers, Carsten

AU - Spirkl, Andreas

AU - Lercher, Johannes A.

PY - 2006

Y1 - 2006

N2 - The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts combining soft Lewis acidic and strong Brønsted acidic functions; the materials showed exceptional catalytic activity for the addition of aniline to styrene, providing the Markownikoff product under kinetically controlled conditions and mainly the anti-Markownikoff product in the thermodynamic regime.

AB - The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts combining soft Lewis acidic and strong Brønsted acidic functions; the materials showed exceptional catalytic activity for the addition of aniline to styrene, providing the Markownikoff product under kinetically controlled conditions and mainly the anti-Markownikoff product in the thermodynamic regime.

UR - http://www.scopus.com/inward/record.url?scp=33745837101&partnerID=8YFLogxK

U2 - 10.1039/b605567b

DO - 10.1039/b605567b

M3 - Article

AN - SCOPUS:33745837101

SN - 1359-7345

SP - 2974

EP - 2976

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids

Abstract

Access to Document

Other files and links

Fingerprint

Cite this