Magnetische nichtäquivalenz und konformationen in a̋thyl-, benzyl- und isopropyl-substituierten 3H-Indolen

H. Kessler, B. Zeeh

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The magnetic nonequivalence of geminal X groups in 3H-indoles containing CX2Y groups at C-3 may be explained by conformational considerations. In the case of ethyl and benzyl derivatives an equilibrium between two energetically similar rotamers is assumed whereas in the case of isopropyl substituted derivatives one rotamer is strongly favoured at room temperature.

Original languageGerman
Pages (from-to)6825-6831
Number of pages7
Issue number23
StatePublished - 1968
Externally publishedYes

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