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Mössbauer Effect Studies of 57Co and 57Fe in β‐Rhombohedral Boron

  • Technical University of Munich

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

The behavior of 57Fe and 57Co doped β‐rhombohedral boron was investigated by means of Mössbauer spectroscopy. Samples prepared by diffusing 57Fe at temperatures above 1000 °C and 57Co at temperatures of 1500 °C or higher showed a reproducible quadrupole interaction and a strongly anisotropic ƒ‐factor. Using combinations of the different parameters obtained from the spectra it was attempted to determine the position of the impurities. There is some evidence for an incorporation within the 28 atom subgroup. It was shown that the sites occupied by Co and Fe do not have a C5 v point symmetry.

Original languageEnglish
Pages (from-to)69-77
Number of pages9
JournalPhysica Status Solidi (B) Basic Research
Volume52
Issue number1
DOIs
StatePublished - 1 Jul 1972

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