Low-temperature fluorescence of the pentafluorophenol radical cation

V. E. Bondybey; J. H. English; Terry A. Miller; C. B. Vaughn

doi:10.1021/j150612a013

Low-temperature fluorescence of the pentafluorophenol radical cation

V. E. Bondybey
, J. H. English
, Terry A. Miller
, C. B. Vaughn

Alcatel-Lucent

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Absorption and laser-induced fluorescence spectra of the pentafluorophenol radical cation are reported and vibrationally analyzed. The fluorescence exhibits a lifetime of 32 ± 2 ns, and its origin at 22 407 cm^-1 is in good agreement with the value derived from photoelectron spectra. The upper state vibrational structure shows a very strong similarity to the C₆F₆⁺ cation. Unlike C₆F₆⁺ or C₆F₅CH₃⁺ the ground-state vibrational levels do not show any evidence of perturbation due to the proximity of the low-lying Ã state.

Original language	English
Pages (from-to)	1667-1670
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	85
Issue number	12
DOIs	https://doi.org/10.1021/j150612a013
State	Published - 1981
Externally published	Yes

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title = "Low-temperature fluorescence of the pentafluorophenol radical cation",

abstract = "Absorption and laser-induced fluorescence spectra of the pentafluorophenol radical cation are reported and vibrationally analyzed. The fluorescence exhibits a lifetime of 32 ± 2 ns, and its origin at 22 407 cm-1 is in good agreement with the value derived from photoelectron spectra. The upper state vibrational structure shows a very strong similarity to the C6F6+ cation. Unlike C6F6+ or C6F5CH3+ the ground-state vibrational levels do not show any evidence of perturbation due to the proximity of the low-lying {\~A} state.",

author = "Bondybey, \{V. E.\} and English, \{J. H.\} and Miller, \{Terry A.\} and Vaughn, \{C. B.\}",

year = "1981",

doi = "10.1021/j150612a013",

language = "English",

volume = "85",

pages = "1667--1670",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

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T1 - Low-temperature fluorescence of the pentafluorophenol radical cation

AU - Bondybey, V. E.

AU - English, J. H.

AU - Miller, Terry A.

AU - Vaughn, C. B.

PY - 1981

Y1 - 1981

N2 - Absorption and laser-induced fluorescence spectra of the pentafluorophenol radical cation are reported and vibrationally analyzed. The fluorescence exhibits a lifetime of 32 ± 2 ns, and its origin at 22 407 cm-1 is in good agreement with the value derived from photoelectron spectra. The upper state vibrational structure shows a very strong similarity to the C6F6+ cation. Unlike C6F6+ or C6F5CH3+ the ground-state vibrational levels do not show any evidence of perturbation due to the proximity of the low-lying Ã state.

AB - Absorption and laser-induced fluorescence spectra of the pentafluorophenol radical cation are reported and vibrationally analyzed. The fluorescence exhibits a lifetime of 32 ± 2 ns, and its origin at 22 407 cm-1 is in good agreement with the value derived from photoelectron spectra. The upper state vibrational structure shows a very strong similarity to the C6F6+ cation. Unlike C6F6+ or C6F5CH3+ the ground-state vibrational levels do not show any evidence of perturbation due to the proximity of the low-lying Ã state.

UR - https://www.scopus.com/pages/publications/33845558504

U2 - 10.1021/j150612a013

DO - 10.1021/j150612a013

M3 - Article

AN - SCOPUS:33845558504

SN - 0022-3654

VL - 85

SP - 1667

EP - 1670

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 12

ER -

Low-temperature fluorescence of the pentafluorophenol radical cation

Abstract

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