Low-temperature approach to high surface ZnO nanopowders and a non-aqueous synthesis of ZnO colloids using the single-source precursor [MeZnOSiMe3]4 and related zinc siloxides

Julia Hambrock; Stefan Rabe; Klaus Merz; Alexander Birkner; Andreas Wohlfart; Roland A. Fischer; Matthias Driess

doi:10.1039/b301172k

Low-temperature approach to high surface ZnO nanopowders and a non-aqueous synthesis of ZnO colloids using the single-source precursor [MeZnOSiMe₃]₄ and related zinc siloxides

Julia Hambrock, Stefan Rabe, Klaus Merz, Alexander Birkner, Andreas Wohlfart, Roland A. Fischer, Matthias Driess

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

We present the temperature-dependent thermolysis of siloxy-substituted ZnO single-source precursors into zinc and zinc oxide, respectively. The solid-state pyrolysis at low temperatures leads to the formation of ZnO powder with a very high surface area whereas the thermolysis in solution yields ZnO colloids. The materials are characterized by UV/VIS, photoluminescence, X-Ray Diffraction (XRD), and Transmission Electron Microscopy (TEM).

Original language	English
Pages (from-to)	1731-1736
Number of pages	6
Journal	Journal of Materials Chemistry
Volume	13
Issue number	7
DOIs	https://doi.org/10.1039/b301172k
State	Published - 1 Jul 2003
Externally published	Yes

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title = "Low-temperature approach to high surface ZnO nanopowders and a non-aqueous synthesis of ZnO colloids using the single-source precursor [MeZnOSiMe3]4 and related zinc siloxides",

abstract = "We present the temperature-dependent thermolysis of siloxy-substituted ZnO single-source precursors into zinc and zinc oxide, respectively. The solid-state pyrolysis at low temperatures leads to the formation of ZnO powder with a very high surface area whereas the thermolysis in solution yields ZnO colloids. The materials are characterized by UV/VIS, photoluminescence, X-Ray Diffraction (XRD), and Transmission Electron Microscopy (TEM).",

author = "Julia Hambrock and Stefan Rabe and Klaus Merz and Alexander Birkner and Andreas Wohlfart and Fischer, {Roland A.} and Matthias Driess",

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Low-temperature approach to high surface ZnO nanopowders and a non-aqueous synthesis of ZnO colloids using the single-source precursor [MeZnOSiMe₃]₄ and related zinc siloxides. / Hambrock, Julia; Rabe, Stefan; Merz, Klaus et al.
In: Journal of Materials Chemistry, Vol. 13, No. 7, 01.07.2003, p. 1731-1736.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Low-temperature approach to high surface ZnO nanopowders and a non-aqueous synthesis of ZnO colloids using the single-source precursor [MeZnOSiMe3]4 and related zinc siloxides

AU - Hambrock, Julia

AU - Rabe, Stefan

AU - Merz, Klaus

AU - Birkner, Alexander

AU - Wohlfart, Andreas

AU - Fischer, Roland A.

AU - Driess, Matthias

PY - 2003/7/1

Y1 - 2003/7/1

N2 - We present the temperature-dependent thermolysis of siloxy-substituted ZnO single-source precursors into zinc and zinc oxide, respectively. The solid-state pyrolysis at low temperatures leads to the formation of ZnO powder with a very high surface area whereas the thermolysis in solution yields ZnO colloids. The materials are characterized by UV/VIS, photoluminescence, X-Ray Diffraction (XRD), and Transmission Electron Microscopy (TEM).

AB - We present the temperature-dependent thermolysis of siloxy-substituted ZnO single-source precursors into zinc and zinc oxide, respectively. The solid-state pyrolysis at low temperatures leads to the formation of ZnO powder with a very high surface area whereas the thermolysis in solution yields ZnO colloids. The materials are characterized by UV/VIS, photoluminescence, X-Ray Diffraction (XRD), and Transmission Electron Microscopy (TEM).

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U2 - 10.1039/b301172k

DO - 10.1039/b301172k

M3 - Article

AN - SCOPUS:0038641130

SN - 0959-9428

VL - 13

SP - 1731

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IS - 7

ER -

Low-temperature approach to high surface ZnO nanopowders and a non-aqueous synthesis of ZnO colloids using the single-source precursor [MeZnOSiMe₃]₄ and related zinc siloxides

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