Long-living light-emitting electrochemical cells - Control through supramolecular interactions

Henk J. Bolink; Eugenio Coronado; Rubén D. Costa; Enrique Ortí; Michele Sessolo; Stefan Graber; Kevin Doyle; Markus Neuburger; Catherine E. Housecroft; Edwin C. Constable

doi:10.1002/adma.200801322

Long-living light-emitting electrochemical cells - Control through supramolecular interactions

Henk J. Bolink, Eugenio Coronado, Rubén D. Costa, Enrique Ortí, Michele Sessolo, Stefan Graber, Kevin Doyle, Markus Neuburger, Catherine E. Housecroft, Edwin C. Constable

Research output: Contribution to journal › Article › peer-review

188 Scopus citations

Abstract

A study was conducted to demonstrate the preparation and characteristics of a supramolecularly caged ionic iridium(III) complex [Ir(ppy) ₂(Hpbpy)][PF₆], where ppy is 2-phenylpyridine and Hpbpy is 6-phenyl-2,2'-bipyridine. The second complex was compared with the parent complex, [Ir(ppy)₂(Hpbpy)][PF₆] during investigations. It was demonstrated that the lifetime of a simple electroluminescent device employing air-stable electrodes and supramolecularly-caged complex, as the active component is more than 3000 hours at an average luminance of 200 cd m^-2, while operating at a driving voltage of 3 volts. The large increase in lifetime was obtained, without sacrificing the device turn-on time.

Original language	English
Pages (from-to)	3910-3913
Number of pages	4
Journal	Advanced Materials
Volume	20
Issue number	20
DOIs	https://doi.org/10.1002/adma.200801322
State	Published - 17 Oct 2008
Externally published	Yes

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title = "Long-living light-emitting electrochemical cells - Control through supramolecular interactions",

abstract = "A study was conducted to demonstrate the preparation and characteristics of a supramolecularly caged ionic iridium(III) complex [Ir(ppy) 2(Hpbpy)][PF6], where ppy is 2-phenylpyridine and Hpbpy is 6-phenyl-2,2'-bipyridine. The second complex was compared with the parent complex, [Ir(ppy)2(Hpbpy)][PF6] during investigations. It was demonstrated that the lifetime of a simple electroluminescent device employing air-stable electrodes and supramolecularly-caged complex, as the active component is more than 3000 hours at an average luminance of 200 cd m-2, while operating at a driving voltage of 3 volts. The large increase in lifetime was obtained, without sacrificing the device turn-on time.",

author = "Bolink, {Henk J.} and Eugenio Coronado and Costa, {Rub{\'e}n D.} and Enrique Ort{\'i} and Michele Sessolo and Stefan Graber and Kevin Doyle and Markus Neuburger and Housecroft, {Catherine E.} and Constable, {Edwin C.}",

year = "2008",

month = oct,

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doi = "10.1002/adma.200801322",

language = "English",

volume = "20",

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T1 - Long-living light-emitting electrochemical cells - Control through supramolecular interactions

AU - Bolink, Henk J.

AU - Coronado, Eugenio

AU - Costa, Rubén D.

AU - Ortí, Enrique

AU - Sessolo, Michele

AU - Graber, Stefan

AU - Doyle, Kevin

AU - Neuburger, Markus

AU - Housecroft, Catherine E.

AU - Constable, Edwin C.

PY - 2008/10/17

Y1 - 2008/10/17

N2 - A study was conducted to demonstrate the preparation and characteristics of a supramolecularly caged ionic iridium(III) complex [Ir(ppy) 2(Hpbpy)][PF6], where ppy is 2-phenylpyridine and Hpbpy is 6-phenyl-2,2'-bipyridine. The second complex was compared with the parent complex, [Ir(ppy)2(Hpbpy)][PF6] during investigations. It was demonstrated that the lifetime of a simple electroluminescent device employing air-stable electrodes and supramolecularly-caged complex, as the active component is more than 3000 hours at an average luminance of 200 cd m-2, while operating at a driving voltage of 3 volts. The large increase in lifetime was obtained, without sacrificing the device turn-on time.

AB - A study was conducted to demonstrate the preparation and characteristics of a supramolecularly caged ionic iridium(III) complex [Ir(ppy) 2(Hpbpy)][PF6], where ppy is 2-phenylpyridine and Hpbpy is 6-phenyl-2,2'-bipyridine. The second complex was compared with the parent complex, [Ir(ppy)2(Hpbpy)][PF6] during investigations. It was demonstrated that the lifetime of a simple electroluminescent device employing air-stable electrodes and supramolecularly-caged complex, as the active component is more than 3000 hours at an average luminance of 200 cd m-2, while operating at a driving voltage of 3 volts. The large increase in lifetime was obtained, without sacrificing the device turn-on time.

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VL - 20

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JO - Advanced Materials

JF - Advanced Materials

IS - 20

ER -

Long-living light-emitting electrochemical cells - Control through supramolecular interactions

Abstract

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