Local visualization of catalytic activity at gas evolving electrodes using frequency-dependent scanning electrochemical microscopy

A new concept for the localized characterization of gas evolving electrodes based on scanning electrochemical microscopy (SECM) is suggested. It offers information about the spatial distribution of the predominant locations, which represent the most active catalytic sites, and dynamic characteristics of gas-bubble departure. The knowledge about gas-bubble departure is critical for the assessment and development of new electrode materials for energy applications.