Lithium salicylate monohydrate: A layer structure with carboxylate-bridged Δ- and Λ-[(H2O)Li+]∞ helices

Frank Wiesbrock; Hubert Schmidbaur

doi:10.1039/b312892j

Lithium salicylate monohydrate: A layer structure with carboxylate-bridged Δ- and Λ-[(H₂O)Li⁺]_∞ helices

Frank Wiesbrock, Hubert Schmidbaur

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Lithium salicylate crystallizes from aqueous solutions as the monohydrate (space group P2₁/c). In its layer structure, alternating Δ- and Λ-[(H₂O)Li⁺]_∞ helices run parallel along the b-axis. These helices are double-bridged at the tetracoordinate lithium cations by the carboxylate groups of the salicylate anions.

Original language	English
Pages (from-to)	503-505
Number of pages	3
Journal	CrystEngComm
Volume	5
DOIs	https://doi.org/10.1039/b312892j
State	Published - 5 Dec 2003
Externally published	Yes

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title = "Lithium salicylate monohydrate: A layer structure with carboxylate-bridged Δ- and Λ-[(H2O)Li+]∞ helices",

abstract = "Lithium salicylate crystallizes from aqueous solutions as the monohydrate (space group P21/c). In its layer structure, alternating Δ- and Λ-[(H2O)Li+]∞ helices run parallel along the b-axis. These helices are double-bridged at the tetracoordinate lithium cations by the carboxylate groups of the salicylate anions.",

author = "Frank Wiesbrock and Hubert Schmidbaur",

year = "2003",

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doi = "10.1039/b312892j",

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T2 - A layer structure with carboxylate-bridged Δ- and Λ-[(H2O)Li+]∞ helices

AU - Wiesbrock, Frank

AU - Schmidbaur, Hubert

PY - 2003/12/5

Y1 - 2003/12/5

N2 - Lithium salicylate crystallizes from aqueous solutions as the monohydrate (space group P21/c). In its layer structure, alternating Δ- and Λ-[(H2O)Li+]∞ helices run parallel along the b-axis. These helices are double-bridged at the tetracoordinate lithium cations by the carboxylate groups of the salicylate anions.

AB - Lithium salicylate crystallizes from aqueous solutions as the monohydrate (space group P21/c). In its layer structure, alternating Δ- and Λ-[(H2O)Li+]∞ helices run parallel along the b-axis. These helices are double-bridged at the tetracoordinate lithium cations by the carboxylate groups of the salicylate anions.

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U2 - 10.1039/b312892j

DO - 10.1039/b312892j

M3 - Article

AN - SCOPUS:16244372060

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JF - CrystEngComm

ER -

Lithium salicylate monohydrate: A layer structure with carboxylate-bridged Δ- and Λ-[(H₂O)Li⁺]_∞ helices

Abstract

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