Lithium L-hydrogen-α-glutamate: A layer structure with asymmetrical tunnels formed by nets with two different macrocycles

Frank Wiesbrock; Hubert Schmidbaur

doi:10.1039/b304689c

Lithium L-hydrogen-α-glutamate: A layer structure with asymmetrical tunnels formed by nets with two different macrocycles

Frank Wiesbrock
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Anhydrous lithium L-hydrogen-α-glutamate Li[L-α-GluH] crystallizes from water with a layer structure (non-centrosymmetric space group P1) in which the tetracoordinate lithium cations are bridged by the glutamate anions in their ammonium form (-NH₃⁺). The resulting 12- and 16-membered rings allow for tunnels running perpendicular to each other in the layers.

Original language	English
Pages (from-to)	262-264
Number of pages	3
Journal	CrystEngComm
Volume	5
DOIs	https://doi.org/10.1039/b304689c
State	Published - 30 Jun 2003

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title = "Lithium L-hydrogen-α-glutamate: A layer structure with asymmetrical tunnels formed by nets with two different macrocycles",

abstract = "Anhydrous lithium L-hydrogen-α-glutamate Li[L-α-GluH] crystallizes from water with a layer structure (non-centrosymmetric space group P1) in which the tetracoordinate lithium cations are bridged by the glutamate anions in their ammonium form (-NH3+). The resulting 12- and 16-membered rings allow for tunnels running perpendicular to each other in the layers.",

author = "Frank Wiesbrock and Hubert Schmidbaur",

year = "2003",

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doi = "10.1039/b304689c",

language = "English",

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journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

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AU - Wiesbrock, Frank

AU - Schmidbaur, Hubert

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Y1 - 2003/6/30

N2 - Anhydrous lithium L-hydrogen-α-glutamate Li[L-α-GluH] crystallizes from water with a layer structure (non-centrosymmetric space group P1) in which the tetracoordinate lithium cations are bridged by the glutamate anions in their ammonium form (-NH3+). The resulting 12- and 16-membered rings allow for tunnels running perpendicular to each other in the layers.

AB - Anhydrous lithium L-hydrogen-α-glutamate Li[L-α-GluH] crystallizes from water with a layer structure (non-centrosymmetric space group P1) in which the tetracoordinate lithium cations are bridged by the glutamate anions in their ammonium form (-NH3+). The resulting 12- and 16-membered rings allow for tunnels running perpendicular to each other in the layers.

UR - https://www.scopus.com/pages/publications/1342273184

U2 - 10.1039/b304689c

DO - 10.1039/b304689c

M3 - Article

AN - SCOPUS:1342273184

SN - 1466-8033

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SP - 262

EP - 264

JO - CrystEngComm

JF - CrystEngComm

ER -

Lithium L-hydrogen-α-glutamate: A layer structure with asymmetrical tunnels formed by nets with two different macrocycles

Abstract

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