Linker functionalisation triggers an alternative 3D-topology for Zn-isophthalate-4,4′-bipyridine frameworks

Andreas Schneemann; Robin Rudolf; Sebastian Henke; Yukiko Takahashi; Hung Banh; Inke Hante; Christian Schneider; Shin Ichiro Noro; Roland A. Fischer

doi:10.1039/c7dt01195d

Linker functionalisation triggers an alternative 3D-topology for Zn-isophthalate-4,4′-bipyridine frameworks

Andreas Schneemann, Robin Rudolf, Sebastian Henke, Yukiko Takahashi, Hung Banh, Inke Hante, Christian Schneider, Shin Ichiro Noro, Roland A. Fischer

Chair of Inorganic and Organometallic Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A series of four Zn²⁺ metal-organic frameworks containing functionalised isophthalate linkers and 4,4′-bipyridine pillars have been prepared and characterised. Isophthalates which contain -OC₃H_2n+1 alkoxy side chains (with n = 1, 2 or 3) form frameworks with a 3D pillared-layer topology instead of the typical 2D layer topology of the renowned coordination polymers with an interdigitated structure (CIDs), which is found for shorter -OC₂H₅ side chains. The gas adsorption properties of the materials were analysed using N₂, CO₂ and O₂ adsorption measurements at low temperatures.

Original language	English
Pages (from-to)	8198-8203
Number of pages	6
Journal	Dalton Transactions
Volume	46
Issue number	25
DOIs	https://doi.org/10.1039/c7dt01195d
State	Published - 2017

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title = "Linker functionalisation triggers an alternative 3D-topology for Zn-isophthalate-4,4′-bipyridine frameworks",

abstract = "A series of four Zn2+ metal-organic frameworks containing functionalised isophthalate linkers and 4,4′-bipyridine pillars have been prepared and characterised. Isophthalates which contain -OC3H2n+1 alkoxy side chains (with n = 1, 2 or 3) form frameworks with a 3D pillared-layer topology instead of the typical 2D layer topology of the renowned coordination polymers with an interdigitated structure (CIDs), which is found for shorter -OC2H5 side chains. The gas adsorption properties of the materials were analysed using N2, CO2 and O2 adsorption measurements at low temperatures.",

author = "Andreas Schneemann and Robin Rudolf and Sebastian Henke and Yukiko Takahashi and Hung Banh and Inke Hante and Christian Schneider and Noro, {Shin Ichiro} and Fischer, {Roland A.}",

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T1 - Linker functionalisation triggers an alternative 3D-topology for Zn-isophthalate-4,4′-bipyridine frameworks

AU - Schneemann, Andreas

AU - Rudolf, Robin

AU - Henke, Sebastian

AU - Takahashi, Yukiko

AU - Banh, Hung

AU - Hante, Inke

AU - Schneider, Christian

AU - Noro, Shin Ichiro

AU - Fischer, Roland A.

PY - 2017

Y1 - 2017

N2 - A series of four Zn2+ metal-organic frameworks containing functionalised isophthalate linkers and 4,4′-bipyridine pillars have been prepared and characterised. Isophthalates which contain -OC3H2n+1 alkoxy side chains (with n = 1, 2 or 3) form frameworks with a 3D pillared-layer topology instead of the typical 2D layer topology of the renowned coordination polymers with an interdigitated structure (CIDs), which is found for shorter -OC2H5 side chains. The gas adsorption properties of the materials were analysed using N2, CO2 and O2 adsorption measurements at low temperatures.

AB - A series of four Zn2+ metal-organic frameworks containing functionalised isophthalate linkers and 4,4′-bipyridine pillars have been prepared and characterised. Isophthalates which contain -OC3H2n+1 alkoxy side chains (with n = 1, 2 or 3) form frameworks with a 3D pillared-layer topology instead of the typical 2D layer topology of the renowned coordination polymers with an interdigitated structure (CIDs), which is found for shorter -OC2H5 side chains. The gas adsorption properties of the materials were analysed using N2, CO2 and O2 adsorption measurements at low temperatures.

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SN - 1477-9226

VL - 46

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 25

ER -

Linker functionalisation triggers an alternative 3D-topology for Zn-isophthalate-4,4′-bipyridine frameworks

Abstract

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