TY - JOUR
T1 - Linear coinage metal complexes stabilized by a group 13 metalloid ligand
AU - Prabusankar, Ganesan
AU - Gonzalez-Gallardo, Sandra
AU - Doddi, Adinarayana
AU - Gemel, Christian
AU - Winter, Manuela
AU - Fischer, Roland A.
PY - 2010/10
Y1 - 2010/10
N2 - The synthesis and structural characterization of the linear, cationic complex [{(DDP)Ga}2Cu][OTf]·2C6H5F (2, Tf = O2SCF3) stabilized by the monodentate, gallium-based ligand Ga(DDP) (DDP = [HC{(CMe)N(2,6-iPr2C6H3)} 2]-), as well as NMR spectroscopic evidence for the formation of the corresponding silver compound [{(DDP)Ga}2Ag][Al(hfip)4] (3, hfip = [OC(H)(CF3)2]), are reported. The remarkable steric properties of this gallium-based ligand permit the stabilization of 2, which exhibits an unusual linear geometry and a coordination number of two.
AB - The synthesis and structural characterization of the linear, cationic complex [{(DDP)Ga}2Cu][OTf]·2C6H5F (2, Tf = O2SCF3) stabilized by the monodentate, gallium-based ligand Ga(DDP) (DDP = [HC{(CMe)N(2,6-iPr2C6H3)} 2]-), as well as NMR spectroscopic evidence for the formation of the corresponding silver compound [{(DDP)Ga}2Ag][Al(hfip)4] (3, hfip = [OC(H)(CF3)2]), are reported. The remarkable steric properties of this gallium-based ligand permit the stabilization of 2, which exhibits an unusual linear geometry and a coordination number of two.
KW - Copper
KW - Gallium
KW - Metal-metal interactions
KW - Reduction
KW - Silver
UR - http://www.scopus.com/inward/record.url?scp=77957807301&partnerID=8YFLogxK
U2 - 10.1002/ejic.201000616
DO - 10.1002/ejic.201000616
M3 - Article
AN - SCOPUS:77957807301
SN - 1434-1948
SP - 4415
EP - 4418
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 28
ER -