Ligand-protected strain-free diarylgermylenes

Gerald L. Wegner, Raphael J.F. Berger, Annette Schier, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

47 Scopus citations

Abstract

Reaction of 2 molar equiv of 2,6-di(1′-naphthyl)phenyllithium with bis[bis(trimethylsilyl)-amino]germylene afforded the red, crystalline, stable bis[2,6-bis(1-naphthyl)phenyl]germylene [(bisap)2Ge, 6] in good yield. The structure of the solvate 6·C6H6 was determined by single-crystal X-ray methods. The molecule features a largely strain-free conformation with a C-Ge-C angle of 102.72(9)° and Ge-C distances of 2.036(2) and 2.030(2) Å. These parameters are very close to those calculated for the diphenylgermylene prototype by ab initio methods [101.6°, 2.006 Å]. The two new wing-like 2,6-di(1-naphthyl)phenyl substituents appear to protect the germylene center of 6 in a very efficient way without inducing destabilizing distortions. Bis[2,4,6-triphenyl]germylene [(triph)2Ge, 1] was also prepared. Germylenes 1 and 6 were oxidized to yellow products of the composition (triph)2GeO (2) and (bisap)2GeO (7), respectively. The compounds have been characterized by their mass spectra, which show the parent ions in full accordance with the proposed formulas.

Original languageEnglish
Pages (from-to)418-423
Number of pages6
JournalOrganometallics
Volume20
Issue number3
DOIs
StatePublished - 5 Feb 2001
Externally publishedYes

Fingerprint

Dive into the research topics of 'Ligand-protected strain-free diarylgermylenes'. Together they form a unique fingerprint.

Cite this