Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface

O. Shekhah; H. Wang; T. Strunskus; P. Cyganik; D. Zacher; R. Fischer; C. Wöll

doi:10.1021/la701148z

Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface

O. Shekhah, H. Wang, T. Strunskus, P. Cyganik, D. Zacher, R. Fischer, C. Wöll

Research output: Contribution to journal › Article › peer-review

124 Scopus citations

Abstract

A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH₃. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.

Original language	English
Pages (from-to)	7440-7442
Number of pages	3
Journal	Langmuir
Volume	23
Issue number	14
DOIs	https://doi.org/10.1021/la701148z
State	Published - 3 Jul 2007
Externally published	Yes

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abstract = "A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.",

author = "O. Shekhah and H. Wang and T. Strunskus and P. Cyganik and D. Zacher and R. Fischer and C. W{\"o}ll",

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AU - Shekhah, O.

AU - Wang, H.

AU - Strunskus, T.

AU - Cyganik, P.

AU - Zacher, D.

AU - Fischer, R.

AU - Wöll, C.

PY - 2007/7/3

Y1 - 2007/7/3

N2 - A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.

AB - A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.

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VL - 23

SP - 7440

EP - 7442

JO - Langmuir

JF - Langmuir

IS - 14

ER -

Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface

Abstract

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