Lateral interactions and nonequilibrium in adsorption and desorption. Part 2. A kinetic lattice gas model for (2 × 2)-(3O + NO)/Ru(0 0 1)

S. H. Payne; J. S. McEwen; H. J. Kreuzer; D. Menzel

doi:10.1016/j.susc.2006.07.019

Lateral interactions and nonequilibrium in adsorption and desorption. Part 2. A kinetic lattice gas model for (2 × 2)-(3O + NO)/Ru(0 0 1)

S. H. Payne, J. S. McEwen, H. J. Kreuzer, D. Menzel

Chair of Experimental Physics

Dalhousie University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A kinetic lattice gas model is set up to study nonequilibrium effects in thermal desorption caused by limited mobility in the adsorbate. Treating the theoretical desorption spectra as input data we show that nonequilibrium effects must show up when different types of Arrhenius analyses, such as threshold and isosteric methods, are applied. We obtain estimates of the lateral NO interaction energies. The theory developed here has broader applicability beyond the present system.

Original language	English
Pages (from-to)	4660-4669
Number of pages	10
Journal	Surface Science
Volume	600
Issue number	19
DOIs	https://doi.org/10.1016/j.susc.2006.07.019
State	Published - 1 Oct 2006

Keywords

Models of surface kinetics
Nonequilibrium statistical mechanics
Surface diffusion
Thermal desorption

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10.1016/j.susc.2006.07.019

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title = "Lateral interactions and nonequilibrium in adsorption and desorption. Part 2. A kinetic lattice gas model for (2 × 2)-(3O + NO)/Ru(0 0 1)",

abstract = "A kinetic lattice gas model is set up to study nonequilibrium effects in thermal desorption caused by limited mobility in the adsorbate. Treating the theoretical desorption spectra as input data we show that nonequilibrium effects must show up when different types of Arrhenius analyses, such as threshold and isosteric methods, are applied. We obtain estimates of the lateral NO interaction energies. The theory developed here has broader applicability beyond the present system.",

keywords = "Models of surface kinetics, Nonequilibrium statistical mechanics, Surface diffusion, Thermal desorption",

author = "Payne, {S. H.} and McEwen, {J. S.} and Kreuzer, {H. J.} and D. Menzel",

note = "Funding Information: This work was supported by grants from the Natural Sciences and Engineering Research Council of Canada and by the Office of Naval Research. ",

year = "2006",

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T1 - Lateral interactions and nonequilibrium in adsorption and desorption. Part 2. A kinetic lattice gas model for (2 × 2)-(3O + NO)/Ru(0 0 1)

AU - Payne, S. H.

AU - McEwen, J. S.

AU - Kreuzer, H. J.

AU - Menzel, D.

N1 - Funding Information: This work was supported by grants from the Natural Sciences and Engineering Research Council of Canada and by the Office of Naval Research.

PY - 2006/10/1

Y1 - 2006/10/1

N2 - A kinetic lattice gas model is set up to study nonequilibrium effects in thermal desorption caused by limited mobility in the adsorbate. Treating the theoretical desorption spectra as input data we show that nonequilibrium effects must show up when different types of Arrhenius analyses, such as threshold and isosteric methods, are applied. We obtain estimates of the lateral NO interaction energies. The theory developed here has broader applicability beyond the present system.

AB - A kinetic lattice gas model is set up to study nonequilibrium effects in thermal desorption caused by limited mobility in the adsorbate. Treating the theoretical desorption spectra as input data we show that nonequilibrium effects must show up when different types of Arrhenius analyses, such as threshold and isosteric methods, are applied. We obtain estimates of the lateral NO interaction energies. The theory developed here has broader applicability beyond the present system.

KW - Models of surface kinetics

KW - Nonequilibrium statistical mechanics

KW - Surface diffusion

KW - Thermal desorption

UR - http://www.scopus.com/inward/record.url?scp=33749238018&partnerID=8YFLogxK

U2 - 10.1016/j.susc.2006.07.019

DO - 10.1016/j.susc.2006.07.019

M3 - Article

AN - SCOPUS:33749238018

SN - 0039-6028

VL - 600

SP - 4660

EP - 4669

JO - Surface Science

JF - Surface Science

IS - 19

ER -

Lateral interactions and nonequilibrium in adsorption and desorption. Part 2. A kinetic lattice gas model for (2 × 2)-(3O + NO)/Ru(0 0 1)

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Keywords

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