Laser-induced fluorescence spectrum of matrix-isolated C6H8+

V. E. Bondybey, J. H. English, Terry A. Miller

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A laser-induced fluorescence excitation and resolved emission spectrum of the radical cation of 1,3,5-hexatriene has been observed in a Ne matrix. Analysis of these spectra yield vibrational frequencies for both the ground X ̃2Au and excited A ̃2Bg states of the ion. Observations are reported concerning the photoionization process, emission quantum yield, and ion fragmentation. Matrix site effects and production in the gas phase are also discussed.

Original languageEnglish
Pages (from-to)200-208
Number of pages9
JournalJournal of Molecular Spectroscopy
Volume80
Issue number1
DOIs
StatePublished - Mar 1980
Externally publishedYes

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