Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

M. F. Cai; C. C. Carter; Terry A. Miller; V. E. Bondybey

doi:10.1016/0301-0104(91)87023-O

Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

M. F. Cai
, C. C. Carter
, Terry A. Miller
, V. E. Bondybey

Chair of Physical Chemistry

Ohio State University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The laser induced fluorescence excitation spectra of the E³Σ_g-X ³Π_u, F³Σ_g-X ³Π_u, and G ³Π_g-X ³Π_u transitions of Al₂ have been recorded. Rotationally resolved spectra have been obtained for the F³Σ_g-X ³Π_u, and G ³Π_g-X ³Π_u transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.

Original language	English
Pages (from-to)	233-245
Number of pages	13
Journal	Chemical Physics
Volume	155
Issue number	2
DOIs	https://doi.org/10.1016/0301-0104(91)87023-O
State	Published - 15 Aug 1991

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@article{dd9f280571e64077be44542e88e66edc,

title = "Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer",

abstract = "The laser induced fluorescence excitation spectra of the E3Σg-X 3Πu, F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions of Al2 have been recorded. Rotationally resolved spectra have been obtained for the F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.",

author = "Cai, \{M. F.\} and Carter, \{C. C.\} and Miller, \{Terry A.\} and Bondybey, \{V. E.\}",

note = "Funding Information: The support of this work by the National Science Foundation under grants CHE8803169 and CHE9005963 and by The Ohio StateU niversity Re-searchG rant Program is gratefully acknowledged.",

year = "1991",

month = aug,

day = "15",

doi = "10.1016/0301-0104(91)87023-O",

language = "English",

volume = "155",

pages = "233--245",

journal = "Chemical Physics",

issn = "0301-0104",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

AU - Cai, M. F.

AU - Carter, C. C.

AU - Miller, Terry A.

AU - Bondybey, V. E.

N1 - Funding Information: The support of this work by the National Science Foundation under grants CHE8803169 and CHE9005963 and by The Ohio StateU niversity Re-searchG rant Program is gratefully acknowledged.

PY - 1991/8/15

Y1 - 1991/8/15

N2 - The laser induced fluorescence excitation spectra of the E3Σg-X 3Πu, F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions of Al2 have been recorded. Rotationally resolved spectra have been obtained for the F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.

AB - The laser induced fluorescence excitation spectra of the E3Σg-X 3Πu, F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions of Al2 have been recorded. Rotationally resolved spectra have been obtained for the F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.

UR - https://www.scopus.com/pages/publications/0001091613

U2 - 10.1016/0301-0104(91)87023-O

DO - 10.1016/0301-0104(91)87023-O

M3 - Article

AN - SCOPUS:0001091613

SN - 0301-0104

VL - 155

SP - 233

EP - 245

JO - Chemical Physics

JF - Chemical Physics

IS - 2

ER -

Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

Abstract

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