Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

M. F. Cai, C. C. Carter, Terry A. Miller, V. E. Bondybey

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Abstract

The laser induced fluorescence excitation spectra of the E3Σg-X 3Πu, F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions of Al2 have been recorded. Rotationally resolved spectra have been obtained for the F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.

Original languageEnglish
Pages (from-to)233-245
Number of pages13
JournalChemical Physics
Volume155
Issue number2
DOIs
StatePublished - 15 Aug 1991

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