Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

M. F. Cai; C. C. Carter; Terry A. Miller; V. E. Bondybey

doi:10.1016/0301-0104(91)87023-O

Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

M. F. Cai, C. C. Carter, Terry A. Miller, V. E. Bondybey

Chair of Physical Chemistry

Ohio State University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The laser induced fluorescence excitation spectra of the E³Σ_g-X ³Π_u, F³Σ_g-X ³Π_u, and G ³Π_g-X ³Π_u transitions of Al₂ have been recorded. Rotationally resolved spectra have been obtained for the F³Σ_g-X ³Π_u, and G ³Π_g-X ³Π_u transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.

Original language	English
Pages (from-to)	233-245
Number of pages	13
Journal	Chemical Physics
Volume	155
Issue number	2
DOIs	https://doi.org/10.1016/0301-0104(91)87023-O
State	Published - 15 Aug 1991

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@article{dd9f280571e64077be44542e88e66edc,

title = "Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer",

abstract = "The laser induced fluorescence excitation spectra of the E3Σg-X 3Πu, F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions of Al2 have been recorded. Rotationally resolved spectra have been obtained for the F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.",

author = "Cai, {M. F.} and Carter, {C. C.} and Miller, {Terry A.} and Bondybey, {V. E.}",

note = "Funding Information: The support of this work by the National Science Foundation under grants CHE8803169 and CHE9005963 and by The Ohio StateU niversity Re-searchG rant Program is gratefully acknowledged.",

year = "1991",

month = aug,

day = "15",

doi = "10.1016/0301-0104(91)87023-O",

language = "English",

volume = "155",

pages = "233--245",

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TY - JOUR

T1 - Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

AU - Cai, M. F.

AU - Carter, C. C.

AU - Miller, Terry A.

AU - Bondybey, V. E.

N1 - Funding Information: The support of this work by the National Science Foundation under grants CHE8803169 and CHE9005963 and by The Ohio StateU niversity Re-searchG rant Program is gratefully acknowledged.

PY - 1991/8/15

Y1 - 1991/8/15

N2 - The laser induced fluorescence excitation spectra of the E3Σg-X 3Πu, F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions of Al2 have been recorded. Rotationally resolved spectra have been obtained for the F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.

AB - The laser induced fluorescence excitation spectra of the E3Σg-X 3Πu, F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions of Al2 have been recorded. Rotationally resolved spectra have been obtained for the F3Σg-X 3Πu, and G 3Πg-X 3Πu transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.

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U2 - 10.1016/0301-0104(91)87023-O

DO - 10.1016/0301-0104(91)87023-O

M3 - Article

AN - SCOPUS:0001091613

SN - 0301-0104

VL - 155

SP - 233

EP - 245

JO - Chemical Physics

JF - Chemical Physics

IS - 2

ER -

Laser excitation and resolved emission spectra of supersonically cooled aluminum dimer

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