Abstract
Complexes of the Lanthanides, V1.–Structural Chemistry of Monomeric and Dimeric Rare Earth Alkoxides The first sublimable monomeric yttrium „CH‐alkoxide” Y[OC‐(iPr)(tBu)2]3 (3) is obtained by the reaction of „CH‐alcohol” HOCiPr(tBu)2 („H‐proditox”, 1) with Y[N(SiMe3)2]3 (2). The importance of metal‐ion size and ligand sphere for nucleation is demonstrated for the system „Ln/ditox/acetonitrile”. The crystal structure data of dimeric 4 (Ln=Nd) and monomeric 5 (Ln=Dy) once again support the ionic nature of lanthanide alkoxide complexes.
| Original language | German |
|---|---|
| Pages (from-to) | 1533-1539 |
| Number of pages | 7 |
| Journal | Chemische Berichte |
| Volume | 126 |
| Issue number | 7 |
| DOIs | |
| State | Published - Jul 1993 |