Lanthanoiden‐Komplexe, II. Tris(tert‐butylcyclopentadienyl)neodym, ‐dysprosium und ‐thulium. Kristall‐ und Molekülstruktur von Bis(tert‐butylcyclopentadienyl)‐hydroxidoneodym und ‐dysprosium

Wolfgang A. Herrmann; Reiner Anwander; Matthias Kleine; Karl Öfele; Jürgen Riede; Wolfgang Scherer

doi:10.1002/cber.19921251111

Lanthanoiden‐Komplexe, II. Tris(tert‐butylcyclopentadienyl)neodym, ‐dysprosium und ‐thulium. Kristall‐ und Molekülstruktur von Bis(tert‐butylcyclopentadienyl)‐hydroxidoneodym und ‐dysprosium

Wolfgang A. Herrmann, Reiner Anwander, Matthias Kleine, Karl Öfele, Jürgen Riede, Wolfgang Scherer

Technical University of Munich

Technical University of Munich

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36 Scopus citations

Abstract

Complexes of the Lanthanides, II¹. – Tris(tert‐butylcyclopentadienyl)neodymium, ‐dysprosium, and ‐thulium. Crystal and Molecular Structure of Bis(tert‐butylcyclopentadienyl)hydroxidoneodymium and ‐dysprosium NdCl₃, DyCl₃, and TmI₃ (1a–c) react with the potassium salt K(tBuCp) (2) of tert‐butylcyclopentadiene in THF to yield the sublimable homoleptic tris(tert‐butylcyclopentadienyl) complexes of formula Ln(tBuCp)₃ (3a–c). The thermal behavior makes these compounds potential precursors for chemical vapour deposition techniques (MOCVD).

Original language	German
Pages (from-to)	2391-2397
Number of pages	7
Journal	Chemische Berichte
Volume	125
Issue number	11
DOIs	https://doi.org/10.1002/cber.19921251111
State	Published - Nov 1992

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Herrmann, W. A., Anwander, R., Kleine, M., Öfele, K., Riede, J., & Scherer, W. (1992). Lanthanoiden‐Komplexe, II. Tris(tert‐butylcyclopentadienyl)neodym, ‐dysprosium und ‐thulium. Kristall‐ und Molekülstruktur von Bis(tert‐butylcyclopentadienyl)‐hydroxidoneodym und ‐dysprosium. Chemische Berichte, 125(11), 2391-2397. https://doi.org/10.1002/cber.19921251111

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title = "Lanthanoiden‐Komplexe, II. Tris(tert‐butylcyclopentadienyl)neodym, ‐dysprosium und ‐thulium. Kristall‐ und Molek{\"u}lstruktur von Bis(tert‐butylcyclopentadienyl)‐hydroxidoneodym und ‐dysprosium",

abstract = "Complexes of the Lanthanides, II1. – Tris(tert‐butylcyclopentadienyl)neodymium, ‐dysprosium, and ‐thulium. Crystal and Molecular Structure of Bis(tert‐butylcyclopentadienyl)hydroxidoneodymium and ‐dysprosium NdCl3, DyCl3, and TmI3 (1a–c) react with the potassium salt K(tBuCp) (2) of tert‐butylcyclopentadiene in THF to yield the sublimable homoleptic tris(tert‐butylcyclopentadienyl) complexes of formula Ln(tBuCp)3 (3a–c). The thermal behavior makes these compounds potential precursors for chemical vapour deposition techniques (MOCVD).",

keywords = "Cyclopentadienyl ligand, Dysprosium complexes, Lanthanides, Neodymium complexes, Thermochemistry, Thulium complexes",

author = "Herrmann, {Wolfgang A.} and Reiner Anwander and Matthias Kleine and Karl {\"O}fele and J{\"u}rgen Riede and Wolfgang Scherer",

year = "1992",

month = nov,

doi = "10.1002/cber.19921251111",

language = "Deutsch",

volume = "125",

pages = "2391--2397",

journal = "Chemische Berichte",

issn = "0009-2940",

publisher = "John Wiley and Sons Ltd",

number = "11",

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Herrmann, WA, Anwander, R, Kleine, M, Öfele, K, Riede, J & Scherer, W 1992, 'Lanthanoiden‐Komplexe, II. Tris(tert‐butylcyclopentadienyl)neodym, ‐dysprosium und ‐thulium. Kristall‐ und Molekülstruktur von Bis(tert‐butylcyclopentadienyl)‐hydroxidoneodym und ‐dysprosium', Chemische Berichte, vol. 125, no. 11, pp. 2391-2397. https://doi.org/10.1002/cber.19921251111

Lanthanoiden‐Komplexe, II. Tris(tert‐butylcyclopentadienyl)neodym, ‐dysprosium und ‐thulium. Kristall‐ und Molekülstruktur von Bis(tert‐butylcyclopentadienyl)‐hydroxidoneodym und ‐dysprosium. / Herrmann, Wolfgang A.; Anwander, Reiner; Kleine, Matthias et al.
In: Chemische Berichte, Vol. 125, No. 11, 11.1992, p. 2391-2397.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Lanthanoiden‐Komplexe, II. Tris(tert‐butylcyclopentadienyl)neodym, ‐dysprosium und ‐thulium. Kristall‐ und Molekülstruktur von Bis(tert‐butylcyclopentadienyl)‐hydroxidoneodym und ‐dysprosium

AU - Herrmann, Wolfgang A.

AU - Anwander, Reiner

AU - Kleine, Matthias

AU - Öfele, Karl

AU - Riede, Jürgen

AU - Scherer, Wolfgang

PY - 1992/11

Y1 - 1992/11

N2 - Complexes of the Lanthanides, II1. – Tris(tert‐butylcyclopentadienyl)neodymium, ‐dysprosium, and ‐thulium. Crystal and Molecular Structure of Bis(tert‐butylcyclopentadienyl)hydroxidoneodymium and ‐dysprosium NdCl3, DyCl3, and TmI3 (1a–c) react with the potassium salt K(tBuCp) (2) of tert‐butylcyclopentadiene in THF to yield the sublimable homoleptic tris(tert‐butylcyclopentadienyl) complexes of formula Ln(tBuCp)3 (3a–c). The thermal behavior makes these compounds potential precursors for chemical vapour deposition techniques (MOCVD).

AB - Complexes of the Lanthanides, II1. – Tris(tert‐butylcyclopentadienyl)neodymium, ‐dysprosium, and ‐thulium. Crystal and Molecular Structure of Bis(tert‐butylcyclopentadienyl)hydroxidoneodymium and ‐dysprosium NdCl3, DyCl3, and TmI3 (1a–c) react with the potassium salt K(tBuCp) (2) of tert‐butylcyclopentadiene in THF to yield the sublimable homoleptic tris(tert‐butylcyclopentadienyl) complexes of formula Ln(tBuCp)3 (3a–c). The thermal behavior makes these compounds potential precursors for chemical vapour deposition techniques (MOCVD).

KW - Cyclopentadienyl ligand

KW - Dysprosium complexes

KW - Lanthanides

KW - Neodymium complexes

KW - Thermochemistry

KW - Thulium complexes

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DO - 10.1002/cber.19921251111

M3 - Artikel

AN - SCOPUS:0010897345

SN - 0009-2940

VL - 125

SP - 2391

EP - 2397

JO - Chemische Berichte

JF - Chemische Berichte

IS - 11

ER -

Lanthanoiden‐Komplexe, II. Tris(tert‐butylcyclopentadienyl)neodym, ‐dysprosium und ‐thulium. Kristall‐ und Molekülstruktur von Bis(tert‐butylcyclopentadienyl)‐hydroxidoneodym und ‐dysprosium

Abstract

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