Komplexe mit Phosphinomethan- und methanidliganden. XIV. [μ-(Me3Si)C(PMe2)2]3Ge4Cl2+ [GeCl3]-, ein di-spirocyclischer Germylen-Kationkomplex mit gewinkelter Ge4-Kette

Hans Heinz Karsch; Brigitte Deubelly; Jürgen Riede; Gerhard Müller

doi:10.1016/0022-328X(87)85209-9

Komplexe mit Phosphinomethan- und methanidliganden. XIV. [μ-(Me₃Si)C(PMe₂)₂]₃Ge₄Cl₂⁺ [GeCl₃]^-, ein di-spirocyclischer Germylen-Kationkomplex mit gewinkelter Ge₄-Kette

Hans Heinz Karsch, Brigitte Deubelly, Jürgen Riede, Gerhard Müller

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Technical University of Munich

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17 Scopus citations

Abstract

The complex {[μ-(Me₃Si)C(PMe₂)₂]₃Ge₄Cl₂}⁺ [GeCl₃]^- (3) is formed in the reaction of GeCl₂ · dioxane with Li[(Me₂P)₂C(SiMe₃] in the presence of magnesium. X-ray crystallography shows it to contain discrete GeCl₃ anions and cationic chains of four germanium atoms with terminal Cl and bridging diphosphinomethanide ligands. Complex 3 is therefore a member of a novel class of homonuclear mixed valency main group element compounds.

Original language	English
Pages (from-to)	C37-C40
Journal	Journal of Organometallic Chemistry
Volume	336
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(87)85209-9
State	Published - 15 Dec 1987

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@article{8733b20c58164686b672b8916c5dce69,

title = "Komplexe mit Phosphinomethan- und methanidliganden. XIV. [μ-(Me3Si)C(PMe2)2]3Ge4Cl2+ [GeCl3]-, ein di-spirocyclischer Germylen-Kationkomplex mit gewinkelter Ge4-Kette",

abstract = "The complex {[μ-(Me3Si)C(PMe2)2]3Ge4Cl2}+ [GeCl3]- (3) is formed in the reaction of GeCl2 · dioxane with Li[(Me2P)2C(SiMe3] in the presence of magnesium. X-ray crystallography shows it to contain discrete GeCl3 anions and cationic chains of four germanium atoms with terminal Cl and bridging diphosphinomethanide ligands. Complex 3 is therefore a member of a novel class of homonuclear mixed valency main group element compounds.",

author = "Karsch, {Hans Heinz} and Brigitte Deubelly and J{\"u}rgen Riede and Gerhard M{\"u}ller",

year = "1987",

month = dec,

day = "15",

doi = "10.1016/0022-328X(87)85209-9",

language = "English",

volume = "336",

pages = "C37--C40",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

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Komplexe mit Phosphinomethan- und methanidliganden. XIV. [μ-(Me₃Si)C(PMe₂)₂]₃Ge₄Cl₂⁺ [GeCl₃]^-, ein di-spirocyclischer Germylen-Kationkomplex mit gewinkelter Ge₄-Kette. / Karsch, Hans Heinz; Deubelly, Brigitte; Riede, Jürgen et al.
In: Journal of Organometallic Chemistry, Vol. 336, No. 3, 15.12.1987, p. C37-C40.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Komplexe mit Phosphinomethan- und methanidliganden. XIV. [μ-(Me3Si)C(PMe2)2]3Ge4Cl2+ [GeCl3]-, ein di-spirocyclischer Germylen-Kationkomplex mit gewinkelter Ge4-Kette

AU - Karsch, Hans Heinz

AU - Deubelly, Brigitte

AU - Riede, Jürgen

AU - Müller, Gerhard

PY - 1987/12/15

Y1 - 1987/12/15

N2 - The complex {[μ-(Me3Si)C(PMe2)2]3Ge4Cl2}+ [GeCl3]- (3) is formed in the reaction of GeCl2 · dioxane with Li[(Me2P)2C(SiMe3] in the presence of magnesium. X-ray crystallography shows it to contain discrete GeCl3 anions and cationic chains of four germanium atoms with terminal Cl and bridging diphosphinomethanide ligands. Complex 3 is therefore a member of a novel class of homonuclear mixed valency main group element compounds.

AB - The complex {[μ-(Me3Si)C(PMe2)2]3Ge4Cl2}+ [GeCl3]- (3) is formed in the reaction of GeCl2 · dioxane with Li[(Me2P)2C(SiMe3] in the presence of magnesium. X-ray crystallography shows it to contain discrete GeCl3 anions and cationic chains of four germanium atoms with terminal Cl and bridging diphosphinomethanide ligands. Complex 3 is therefore a member of a novel class of homonuclear mixed valency main group element compounds.

UR - http://www.scopus.com/inward/record.url?scp=0008816372&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(87)85209-9

DO - 10.1016/0022-328X(87)85209-9

M3 - Article

AN - SCOPUS:0008816372

SN - 0022-328X

VL - 336

SP - C37-C40

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Komplexe mit Phosphinomethan- und methanidliganden. XIV. [μ-(Me₃Si)C(PMe₂)₂]₃Ge₄Cl₂⁺ [GeCl₃]^-, ein di-spirocyclischer Germylen-Kationkomplex mit gewinkelter Ge₄-Kette

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