TY - JOUR
T1 - Komplexchemie reaktiver organischer verbindungen. XVII. Perbromcymantren, tetrabromjodcymantren, 1,2,3-trijodcymantren
AU - Herrmann, Wolfgang A.
AU - Huber, Michael
PY - 1977/10/25
Y1 - 1977/10/25
N2 - Tricarbonyl(η-pentabromocyclopentadienyl)manganese (IIIa), tricarbonyl-(η-tetrabromoiodocyclopentadienyl)manganese (IIIb), and tricarbonyl[η-(1,2,3-triiodo)cyclopentadienyl]manganese (IIIc) are synthesized by the reaction of the pentacarbonylmanganese halides Mn(CO)5X (Ia, b) (X = Br, I) with the halogenated diazocyclopentadiene derivatives IIa and IIb, with yields ≥70%. In the same way, tricarbonyl(η-tetrachloroiodocyclopentadienyl)manganese (IIId) is formed from tetrachlorodiazocyclopentadiene. The new halogen cymantrenes are yellow, air-stable compounds which are slightly sensitive to light, and can be sublimed in high vacuo without decomposition.
AB - Tricarbonyl(η-pentabromocyclopentadienyl)manganese (IIIa), tricarbonyl-(η-tetrabromoiodocyclopentadienyl)manganese (IIIb), and tricarbonyl[η-(1,2,3-triiodo)cyclopentadienyl]manganese (IIIc) are synthesized by the reaction of the pentacarbonylmanganese halides Mn(CO)5X (Ia, b) (X = Br, I) with the halogenated diazocyclopentadiene derivatives IIa and IIb, with yields ≥70%. In the same way, tricarbonyl(η-tetrachloroiodocyclopentadienyl)manganese (IIId) is formed from tetrachlorodiazocyclopentadiene. The new halogen cymantrenes are yellow, air-stable compounds which are slightly sensitive to light, and can be sublimed in high vacuo without decomposition.
UR - http://www.scopus.com/inward/record.url?scp=0001816103&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)84396-X
DO - 10.1016/S0022-328X(00)84396-X
M3 - Artikel
AN - SCOPUS:0001816103
SN - 0022-328X
VL - 140
SP - 55
EP - 61
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -