Isovalent and Mixed‐Valent Ylide Complexes of Gold: The Synthesis of Trinuclear Compounds Having Double Paddlewheel Structure

Hubert Schmidbaur; Christoph Hartmann; Gabriele Reber; Gerhard Müller

doi:10.1002/anie.198711461

Isovalent and Mixed‐Valent Ylide Complexes of Gold: The Synthesis of Trinuclear Compounds Having Double Paddlewheel Structure

Hubert Schmidbaur
, Christoph Hartmann
, Gabriele Reber
, Gerhard Müller

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

The first organo trigold complex, the title compound 1, X = CL, Br, I, is characterized by several unique structural features. In 1, Au^III serves as a spiro atom; its square‐planar coordination is expanded to a pseudooctahedral coordination by two flanking Au ^I centers. Complex 1 is colorless and air‐stable. (Figure Presented.)

Original language	English
Pages (from-to)	1146-1148
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	11
DOIs	https://doi.org/10.1002/anie.198711461
State	Published - Nov 1987

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title = "Isovalent and Mixed‐Valent Ylide Complexes of Gold: The Synthesis of Trinuclear Compounds Having Double Paddlewheel Structure",

abstract = "The first organo trigold complex, the title compound 1, X = CL, Br, I, is characterized by several unique structural features. In 1, AuIII serves as a spiro atom; its square‐planar coordination is expanded to a pseudooctahedral coordination by two flanking Au I centers. Complex 1 is colorless and air‐stable. (Figure Presented.)",

author = "Hubert Schmidbaur and Christoph Hartmann and Gabriele Reber and Gerhard M{\"u}ller",

year = "1987",

month = nov,

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AU - Hartmann, Christoph

AU - Reber, Gabriele

AU - Müller, Gerhard

PY - 1987/11

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N2 - The first organo trigold complex, the title compound 1, X = CL, Br, I, is characterized by several unique structural features. In 1, AuIII serves as a spiro atom; its square‐planar coordination is expanded to a pseudooctahedral coordination by two flanking Au I centers. Complex 1 is colorless and air‐stable. (Figure Presented.)

AB - The first organo trigold complex, the title compound 1, X = CL, Br, I, is characterized by several unique structural features. In 1, AuIII serves as a spiro atom; its square‐planar coordination is expanded to a pseudooctahedral coordination by two flanking Au I centers. Complex 1 is colorless and air‐stable. (Figure Presented.)

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U2 - 10.1002/anie.198711461

DO - 10.1002/anie.198711461

M3 - Article

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SN - 0570-0833

VL - 26

SP - 1146

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 11

ER -

Isovalent and Mixed‐Valent Ylide Complexes of Gold: The Synthesis of Trinuclear Compounds Having Double Paddlewheel Structure

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