TY - JOUR
T1 - Isovalent and Mixed‐Valent Ylide Complexes of Gold
T2 - The Synthesis of Trinuclear Compounds Having Double Paddlewheel Structure
AU - Schmidbaur, Hubert
AU - Hartmann, Christoph
AU - Reber, Gabriele
AU - Müller, Gerhard
PY - 1987/11
Y1 - 1987/11
N2 - The first organo trigold complex, the title compound 1, X = CL, Br, I, is characterized by several unique structural features. In 1, AuIII serves as a spiro atom; its square‐planar coordination is expanded to a pseudooctahedral coordination by two flanking Au I centers. Complex 1 is colorless and air‐stable. (Figure Presented.)
AB - The first organo trigold complex, the title compound 1, X = CL, Br, I, is characterized by several unique structural features. In 1, AuIII serves as a spiro atom; its square‐planar coordination is expanded to a pseudooctahedral coordination by two flanking Au I centers. Complex 1 is colorless and air‐stable. (Figure Presented.)
UR - https://www.scopus.com/pages/publications/84985611109
U2 - 10.1002/anie.198711461
DO - 10.1002/anie.198711461
M3 - Article
AN - SCOPUS:84985611109
SN - 0570-0833
VL - 26
SP - 1146
EP - 1148
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 11
ER -