Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; A general route to [co(C4Me4)(arene)]+

Malcolm R. Cook; Peter Härter; Peter L. Pauson; Ján Šraga

doi:10.1039/DT9870002757

Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; A general route to [co(C₄Me₄)(arene)]⁺

Malcolm R. Cook
, Peter Härter
, Peter L. Pauson
, Ján Šraga

University of Strathclyde

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [{Co(CO)₂(C₄Me₄)}₂] and [Co(CO)₂(C₄Me₄)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C₄Me₄)(arene)]⁺ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)₃(C₄Me₄)]⁺ are also reported.

Original language	English
Pages (from-to)	2757-2760
Number of pages	4
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	11
DOIs	https://doi.org/10.1039/DT9870002757
State	Published - 1987
Externally published	Yes

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title = "Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; A general route to [co(C4Me4)(arene)]+",

abstract = "The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [\{Co(CO)2(C4Me4)\}2] and [Co(CO)2(C4Me4)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C4Me4)(arene)]+ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)3(C4Me4)]+ are also reported.",

author = "Cook, \{Malcolm R.\} and Peter H{\"a}rter and Pauson, \{Peter L.\} and J{\'a}n {\v S}raga",

year = "1987",

doi = "10.1039/DT9870002757",

language = "English",

pages = "2757--2760",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; A general route to [co(C4Me4)(arene)]+

AU - Cook, Malcolm R.

AU - Härter, Peter

AU - Pauson, Peter L.

AU - Šraga, Ján

PY - 1987

Y1 - 1987

N2 - The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [{Co(CO)2(C4Me4)}2] and [Co(CO)2(C4Me4)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C4Me4)(arene)]+ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)3(C4Me4)]+ are also reported.

AB - The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [{Co(CO)2(C4Me4)}2] and [Co(CO)2(C4Me4)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C4Me4)(arene)]+ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)3(C4Me4)]+ are also reported.

UR - https://www.scopus.com/pages/publications/37049084186

U2 - 10.1039/DT9870002757

DO - 10.1039/DT9870002757

M3 - Article

AN - SCOPUS:37049084186

SN - 1472-7773

SP - 2757

EP - 2760

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 11

ER -

Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; A general route to [co(C₄Me₄)(arene)]⁺

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