Isomerism control of diethylstilbestrol by metal surface induced O-H cleavage

Seung Cheol Oh; Julian A. Lloyd; Sybille Fischer; Özge Saǧlam; Anthoula C. Papageorgiou; Katharina Diller; David A. Duncan; Florian Klappenberger; Francesco Allegretti; Joachim Reichert; Johannes V. Barth

doi:10.1039/c8cc06632a

Isomerism control of diethylstilbestrol by metal surface induced O-H cleavage

Seung Cheol Oh, Julian A. Lloyd, Sybille Fischer, Özge Saǧlam, Anthoula C. Papageorgiou, Katharina Diller, David A. Duncan, Florian Klappenberger, Francesco Allegretti, Joachim Reichert, Johannes V. Barth

Chair of Experimental Physics of Functional Spin-Systems

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Diethylstilbestrol (DES) is studied on Ag(111) and Cu(111) surfaces using X-ray photoelectron spectroscopy (XPS) and scanning tunnelling microscopy (STM). We find that DES molecules on the silver surface adsorb intact and adopt a trans-conformation. On the more reactive copper surface, O-H bond cleavage results in molecular adsorption in the cis-conformation, thus providing the means of obtaining different adsorption geometries. The difference in isomerism is reflected in the observed self-assemblies which exhibit room-temperature stability.

Original language	English
Pages (from-to)	12495-12498
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	88
DOIs	https://doi.org/10.1039/c8cc06632a
State	Published - 2018

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title = "Isomerism control of diethylstilbestrol by metal surface induced O-H cleavage",

abstract = "Diethylstilbestrol (DES) is studied on Ag(111) and Cu(111) surfaces using X-ray photoelectron spectroscopy (XPS) and scanning tunnelling microscopy (STM). We find that DES molecules on the silver surface adsorb intact and adopt a trans-conformation. On the more reactive copper surface, O-H bond cleavage results in molecular adsorption in the cis-conformation, thus providing the means of obtaining different adsorption geometries. The difference in isomerism is reflected in the observed self-assemblies which exhibit room-temperature stability.",

author = "Oh, {Seung Cheol} and Lloyd, {Julian A.} and Sybille Fischer and {\"O}zge Saǧlam and Papageorgiou, {Anthoula C.} and Katharina Diller and Duncan, {David A.} and Florian Klappenberger and Francesco Allegretti and Joachim Reichert and Barth, {Johannes V.}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8cc06632a",

language = "English",

volume = "54",

pages = "12495--12498",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "88",

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TY - JOUR

T1 - Isomerism control of diethylstilbestrol by metal surface induced O-H cleavage

AU - Oh, Seung Cheol

AU - Lloyd, Julian A.

AU - Fischer, Sybille

AU - Saǧlam, Özge

AU - Papageorgiou, Anthoula C.

AU - Diller, Katharina

AU - Duncan, David A.

AU - Klappenberger, Florian

AU - Allegretti, Francesco

AU - Reichert, Joachim

AU - Barth, Johannes V.

PY - 2018

Y1 - 2018

N2 - Diethylstilbestrol (DES) is studied on Ag(111) and Cu(111) surfaces using X-ray photoelectron spectroscopy (XPS) and scanning tunnelling microscopy (STM). We find that DES molecules on the silver surface adsorb intact and adopt a trans-conformation. On the more reactive copper surface, O-H bond cleavage results in molecular adsorption in the cis-conformation, thus providing the means of obtaining different adsorption geometries. The difference in isomerism is reflected in the observed self-assemblies which exhibit room-temperature stability.

AB - Diethylstilbestrol (DES) is studied on Ag(111) and Cu(111) surfaces using X-ray photoelectron spectroscopy (XPS) and scanning tunnelling microscopy (STM). We find that DES molecules on the silver surface adsorb intact and adopt a trans-conformation. On the more reactive copper surface, O-H bond cleavage results in molecular adsorption in the cis-conformation, thus providing the means of obtaining different adsorption geometries. The difference in isomerism is reflected in the observed self-assemblies which exhibit room-temperature stability.

UR - http://www.scopus.com/inward/record.url?scp=85055768532&partnerID=8YFLogxK

U2 - 10.1039/c8cc06632a

DO - 10.1039/c8cc06632a

M3 - Article

C2 - 30339165

AN - SCOPUS:85055768532

SN - 1359-7345

VL - 54

SP - 12495

EP - 12498

JO - Chemical Communications

JF - Chemical Communications

IS - 88

ER -

Isomerism control of diethylstilbestrol by metal surface induced O-H cleavage

Abstract

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