(Isocyanide)gold(I) thiosalicylates: Supramolecular assembly based on both auriophilic and hydrogen bonding

Wolfgang Schneider; Andreas Bauer; Hubert Schmidbaur

doi:10.1021/om960682s

(Isocyanide)gold(I) thiosalicylates: Supramolecular assembly based on both auriophilic and hydrogen bonding

Wolfgang Schneider, Andreas Bauer, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

98 Scopus citations

Abstract

Reaction of (RNC)AuCl [R = tert-butyl (1a), mesityl (1b)] with sodium thiosalicylate in the two-phase system water / dichloromethane gives high yields of the corresponding (isocyanide)gold(I) thiosalicylates (2a,b). The solid-state structures of 2a,b have been determined by X-ray diffraction studies. The supramolecular structure of both compounds is governed by Au-Au interactions [2a, Au-Au 3.157(2) Å; 2b, Au-Au 3.3186(5) Å] and hydrogen bonding through the carboxylic acid groups.

Original language	English
Pages (from-to)	5445-5446
Number of pages	2
Journal	Organometallics
Volume	15
Issue number	26
DOIs	https://doi.org/10.1021/om960682s
State	Published - 24 Dec 1996

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title = "(Isocyanide)gold(I) thiosalicylates: Supramolecular assembly based on both auriophilic and hydrogen bonding",

abstract = "Reaction of (RNC)AuCl [R = tert-butyl (1a), mesityl (1b)] with sodium thiosalicylate in the two-phase system water / dichloromethane gives high yields of the corresponding (isocyanide)gold(I) thiosalicylates (2a,b). The solid-state structures of 2a,b have been determined by X-ray diffraction studies. The supramolecular structure of both compounds is governed by Au-Au interactions [2a, Au-Au 3.157(2) {\AA}; 2b, Au-Au 3.3186(5) {\AA}] and hydrogen bonding through the carboxylic acid groups.",

author = "Wolfgang Schneider and Andreas Bauer and Hubert Schmidbaur",

year = "1996",

month = dec,

day = "24",

doi = "10.1021/om960682s",

language = "English",

volume = "15",

pages = "5445--5446",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - (Isocyanide)gold(I) thiosalicylates

T2 - Supramolecular assembly based on both auriophilic and hydrogen bonding

AU - Schneider, Wolfgang

AU - Bauer, Andreas

AU - Schmidbaur, Hubert

PY - 1996/12/24

Y1 - 1996/12/24

N2 - Reaction of (RNC)AuCl [R = tert-butyl (1a), mesityl (1b)] with sodium thiosalicylate in the two-phase system water / dichloromethane gives high yields of the corresponding (isocyanide)gold(I) thiosalicylates (2a,b). The solid-state structures of 2a,b have been determined by X-ray diffraction studies. The supramolecular structure of both compounds is governed by Au-Au interactions [2a, Au-Au 3.157(2) Å; 2b, Au-Au 3.3186(5) Å] and hydrogen bonding through the carboxylic acid groups.

AB - Reaction of (RNC)AuCl [R = tert-butyl (1a), mesityl (1b)] with sodium thiosalicylate in the two-phase system water / dichloromethane gives high yields of the corresponding (isocyanide)gold(I) thiosalicylates (2a,b). The solid-state structures of 2a,b have been determined by X-ray diffraction studies. The supramolecular structure of both compounds is governed by Au-Au interactions [2a, Au-Au 3.157(2) Å; 2b, Au-Au 3.3186(5) Å] and hydrogen bonding through the carboxylic acid groups.

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U2 - 10.1021/om960682s

DO - 10.1021/om960682s

M3 - Article

AN - SCOPUS:0001522341

SN - 0276-7333

VL - 15

SP - 5445

EP - 5446

JO - Organometallics

JF - Organometallics

IS - 26

ER -

(Isocyanide)gold(I) thiosalicylates: Supramolecular assembly based on both auriophilic and hydrogen bonding

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