Iron PCP Pincer Complexes in Three Oxidation States: Reversible Ligand Protonation to Afford an Fe(0) Complex with an Agostic C-H Arene Bond

Keyphrases

• Protonation 100%
• Arenes 100%
• Agostic 100%
• Oxidation State 100%
• Pincer Complexes 100%
• Fe(0) 100%
• Ligand Protonation 100%
• PCP pincer 100%
• Low Spin 50%
• Chloro 50%
• Benzene Solution 50%
• CO 2 50%
• Deprotonated 50%
• Hydrides 50%
• C-H Bond 50%
• Reformation 50%
• Room Temperature 50%
• Acetonitrile 50%
• Ligand Substitution 50%
• Fe(II) Complex 50%
• Nitrosyl Complexes 50%
• One-electron Reduction 50%
• Glass Vials 50%
• Weak Base 50%
• NO Gas 50%
• 1,3-diamines 50%
• Diethylbenzene 50%
• Diamagnetic Complexes 50%
• Agostic Bond 50%
• Ligand Precursor 50%
• C-Cl 50%

Chemistry

• Isopropyl Group 100%
• Pincer Complex 100%
• protonation 100%
• Iron Complex 83%
• Ambient Reaction Temperature 16%
• Diamagnetic 16%
• formation 16%
• Benzene 16%