Interactions of carborane-containing electrophiles with triethyl phosphite. Synthesis of new carborane-containing phosphonates

A. A. Semioskkin; S. G. Inyushin; L. V. Ermanson; P. V. Petrovskii; P. Lemmen; V. I. Bregadze

doi:10.1007/bf02494512

Interactions of carborane-containing electrophiles with triethyl phosphite. Synthesis of new carborane-containing phosphonates

A. A. Semioskkin
, S. G. Inyushin
, L. V. Ermanson
, P. V. Petrovskii
, P. Lemmen
, V. I. Bregadze

Natural Sciences

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The reactions of o-carboran-1-ylethyl mesylates with triethyl phosphite and sodium diethyl phosphite were studied. Carborane-containing phosphonates were synthesized. The reaction of o-carboranylacetyl chloride with triethyl phosphite afforded O,O-diethyl (E)-2-(o-carboran-1-yl)-1-(o-carboran-1-ylacetoxy)vinylphosphonate rather than oxo phosphonate.

Original language	English
Pages (from-to)	1985-1988
Number of pages	4
Journal	Russian Chemical Bulletin
Volume	47
Issue number	10
DOIs	https://doi.org/10.1007/bf02494512
State	Published - Oct 1998

Keywords

Acid chlorides and phosphonates
Carborane-containing mesylates
Triethyl phosphite

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10.1007/bf02494512

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@article{56468c79362f4015b069fc84bd2e3361,

title = "Interactions of carborane-containing electrophiles with triethyl phosphite. Synthesis of new carborane-containing phosphonates",

abstract = "The reactions of o-carboran-1-ylethyl mesylates with triethyl phosphite and sodium diethyl phosphite were studied. Carborane-containing phosphonates were synthesized. The reaction of o-carboranylacetyl chloride with triethyl phosphite afforded O,O-diethyl (E)-2-(o-carboran-1-yl)-1-(o-carboran-1-ylacetoxy)vinylphosphonate rather than oxo phosphonate.",

keywords = "Acid chlorides and phosphonates, Carborane-containing mesylates, Triethyl phosphite",

author = "Semioskkin, \{A. A.\} and Inyushin, \{S. G.\} and Ermanson, \{L. V.\} and Petrovskii, \{P. V.\} and P. Lemmen and Bregadze, \{V. I.\}",

note = "Funding Information: This work was financially supported by the Russian Foundation for Basic Research (Project No. 96-03-32883a), by the Scientific Training Center of Chemistry of Organometallic Compounds (Grant 234, the Federal Target Program {"}Integration'), and by the Volkswagen Foundation.",

year = "1998",

month = oct,

doi = "10.1007/bf02494512",

language = "English",

volume = "47",

pages = "1985--1988",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "10",

}

TY - JOUR

T1 - Interactions of carborane-containing electrophiles with triethyl phosphite. Synthesis of new carborane-containing phosphonates

AU - Semioskkin, A. A.

AU - Inyushin, S. G.

AU - Ermanson, L. V.

AU - Petrovskii, P. V.

AU - Lemmen, P.

AU - Bregadze, V. I.

N1 - Funding Information: This work was financially supported by the Russian Foundation for Basic Research (Project No. 96-03-32883a), by the Scientific Training Center of Chemistry of Organometallic Compounds (Grant 234, the Federal Target Program "Integration'), and by the Volkswagen Foundation.

PY - 1998/10

Y1 - 1998/10

N2 - The reactions of o-carboran-1-ylethyl mesylates with triethyl phosphite and sodium diethyl phosphite were studied. Carborane-containing phosphonates were synthesized. The reaction of o-carboranylacetyl chloride with triethyl phosphite afforded O,O-diethyl (E)-2-(o-carboran-1-yl)-1-(o-carboran-1-ylacetoxy)vinylphosphonate rather than oxo phosphonate.

AB - The reactions of o-carboran-1-ylethyl mesylates with triethyl phosphite and sodium diethyl phosphite were studied. Carborane-containing phosphonates were synthesized. The reaction of o-carboranylacetyl chloride with triethyl phosphite afforded O,O-diethyl (E)-2-(o-carboran-1-yl)-1-(o-carboran-1-ylacetoxy)vinylphosphonate rather than oxo phosphonate.

KW - Acid chlorides and phosphonates

KW - Carborane-containing mesylates

KW - Triethyl phosphite

UR - https://www.scopus.com/pages/publications/0032264512

U2 - 10.1007/bf02494512

DO - 10.1007/bf02494512

M3 - Article

AN - SCOPUS:0032264512

SN - 1066-5285

VL - 47

SP - 1985

EP - 1988

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 10

ER -

Interactions of carborane-containing electrophiles with triethyl phosphite. Synthesis of new carborane-containing phosphonates

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Keywords

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