Interaction of vanadium with iron and antimony at 870 and 1070 K

Vitaliy V. Romaka; Lyubov Romaka; Yuriy Stadnyk; Volodymyr Gvozdetskii; Roman Gladyshevskii; Nathaliya Skryabina; Nathaliya Melnychenko; Viktor Hlukhyy; Thomas Fässler

doi:10.1002/ejic.201101210

Interaction of vanadium with iron and antimony at 870 and 1070 K

Vitaliy V. Romaka, Lyubov Romaka, Yuriy Stadnyk, Volodymyr Gvozdetskii, Roman Gladyshevskii, Nathaliya Skryabina, Nathaliya Melnychenko, Viktor Hlukhyy, Thomas Fässler

Chair of Inorganic Chemistry with Focus on New Materials

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The isothermal sections of the phase diagram of the V-Fe-Sb ternary system have been constructed at 870 and 1070 K by means of X-ray and electron-probe microanalyzer (EPMA) analyses over the whole concentration range. The existence of the one ternary phase, VFeSb, with MgAgAs- and Ni₂In-type structures was observed at 870 and 1070 K, respectively. The solid solution formed based on the binary Fe_2-xSb (Ni₂In-type) compound reaches up to 12 at.-% of V at 870 K and 40 at.-% at 1070 K, respectively. Differential scanning calorimetry (DSC) analysis, magnetic susceptibility measurements, and electronic structure calculations showed the absence of a VFeSb polymorph phase transition and indicate that the hexagonal phase is part of the V_yFe_2-xSb solid solution.

Original language	English
Pages (from-to)	2588-2595
Number of pages	8
Journal	European Journal of Inorganic Chemistry
Issue number	15
DOIs	https://doi.org/10.1002/ejic.201101210
State	Published - May 2012

Keywords

Alloys
Intermetallic phases
Magnetic properties
Metal-metal interactions
Phase diagrams

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10.1002/ejic.201101210

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title = "Interaction of vanadium with iron and antimony at 870 and 1070 K",

abstract = "The isothermal sections of the phase diagram of the V-Fe-Sb ternary system have been constructed at 870 and 1070 K by means of X-ray and electron-probe microanalyzer (EPMA) analyses over the whole concentration range. The existence of the one ternary phase, VFeSb, with MgAgAs- and Ni2In-type structures was observed at 870 and 1070 K, respectively. The solid solution formed based on the binary Fe2-xSb (Ni2In-type) compound reaches up to 12 at.-% of V at 870 K and 40 at.-% at 1070 K, respectively. Differential scanning calorimetry (DSC) analysis, magnetic susceptibility measurements, and electronic structure calculations showed the absence of a VFeSb polymorph phase transition and indicate that the hexagonal phase is part of the VyFe2-xSb solid solution.",

keywords = "Alloys, Intermetallic phases, Magnetic properties, Metal-metal interactions, Phase diagrams",

author = "Romaka, {Vitaliy V.} and Lyubov Romaka and Yuriy Stadnyk and Volodymyr Gvozdetskii and Roman Gladyshevskii and Nathaliya Skryabina and Nathaliya Melnychenko and Viktor Hlukhyy and Thomas F{\"a}ssler",

year = "2012",

month = may,

doi = "10.1002/ejic.201101210",

language = "English",

pages = "2588--2595",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Interaction of vanadium with iron and antimony at 870 and 1070 K

AU - Romaka, Vitaliy V.

AU - Romaka, Lyubov

AU - Stadnyk, Yuriy

AU - Gvozdetskii, Volodymyr

AU - Gladyshevskii, Roman

AU - Skryabina, Nathaliya

AU - Melnychenko, Nathaliya

AU - Hlukhyy, Viktor

AU - Fässler, Thomas

PY - 2012/5

Y1 - 2012/5

N2 - The isothermal sections of the phase diagram of the V-Fe-Sb ternary system have been constructed at 870 and 1070 K by means of X-ray and electron-probe microanalyzer (EPMA) analyses over the whole concentration range. The existence of the one ternary phase, VFeSb, with MgAgAs- and Ni2In-type structures was observed at 870 and 1070 K, respectively. The solid solution formed based on the binary Fe2-xSb (Ni2In-type) compound reaches up to 12 at.-% of V at 870 K and 40 at.-% at 1070 K, respectively. Differential scanning calorimetry (DSC) analysis, magnetic susceptibility measurements, and electronic structure calculations showed the absence of a VFeSb polymorph phase transition and indicate that the hexagonal phase is part of the VyFe2-xSb solid solution.

AB - The isothermal sections of the phase diagram of the V-Fe-Sb ternary system have been constructed at 870 and 1070 K by means of X-ray and electron-probe microanalyzer (EPMA) analyses over the whole concentration range. The existence of the one ternary phase, VFeSb, with MgAgAs- and Ni2In-type structures was observed at 870 and 1070 K, respectively. The solid solution formed based on the binary Fe2-xSb (Ni2In-type) compound reaches up to 12 at.-% of V at 870 K and 40 at.-% at 1070 K, respectively. Differential scanning calorimetry (DSC) analysis, magnetic susceptibility measurements, and electronic structure calculations showed the absence of a VFeSb polymorph phase transition and indicate that the hexagonal phase is part of the VyFe2-xSb solid solution.

KW - Alloys

KW - Intermetallic phases

KW - Magnetic properties

KW - Metal-metal interactions

KW - Phase diagrams

UR - http://www.scopus.com/inward/record.url?scp=84861163322&partnerID=8YFLogxK

U2 - 10.1002/ejic.201101210

DO - 10.1002/ejic.201101210

M3 - Article

AN - SCOPUS:84861163322

SN - 1434-1948

SP - 2588

EP - 2595

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 15

ER -

Interaction of vanadium with iron and antimony at 870 and 1070 K

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