Insertion of organoindium carbenoids into rhodium halide bonds: Revisiting a classic type of transition metal–group 13 metal bond formation

Tobias Steinke; Christian Gemel; Mirza Cokoja; Manuela Winter; Roland A. Fischer

doi:10.1039/b301928d

Insertion of organoindium carbenoids into rhodium halide bonds: Revisiting a classic type of transition metal–group 13 metal bond formation

Tobias Steinke, Christian Gemel, Mirza Cokoja, Manuela Winter, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Insertion of the carbenoid group 13 metal species InCp*(Cp* = pentamethylcyclopentadienyl) and InC(SiMe₃)₃ into the Rh–Cl bonds of ‘(RhCp*Cl₂)₂’ yields the new complexes ‘Cp*Rh(InCp*)₃(Cl)₂’ 1 and ‘Cp*Rh(μ²-Cl)₂(InC(SiMe₃)₃)₃’ 2, respectively, exhibiting novel cage-like intermetallic complexes with In–Cl–In bridges.

Original language	English
Pages (from-to)	1066-1067
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	9
DOIs	https://doi.org/10.1039/b301928d
State	Published - 2003
Externally published	Yes

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title = "Insertion of organoindium carbenoids into rhodium halide bonds: Revisiting a classic type of transition metal–group 13 metal bond formation",

abstract = "Insertion of the carbenoid group 13 metal species InCp*(Cp* = pentamethylcyclopentadienyl) and InC(SiMe3)3 into the Rh–Cl bonds of {\textquoteleft}(RhCp*Cl2)2{\textquoteright} yields the new complexes {\textquoteleft}Cp*Rh(InCp*)3(Cl)2{\textquoteright} 1 and {\textquoteleft}Cp*Rh(μ2-Cl)2(InC(SiMe3)3)3{\textquoteright} 2, respectively, exhibiting novel cage-like intermetallic complexes with In–Cl–In bridges.",

author = "Tobias Steinke and Christian Gemel and Mirza Cokoja and Manuela Winter and Fischer, {Roland A.}",

year = "2003",

doi = "10.1039/b301928d",

language = "English",

volume = "3",

pages = "1066--1067",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "9",

}

TY - JOUR

T1 - Insertion of organoindium carbenoids into rhodium halide bonds

T2 - Revisiting a classic type of transition metal–group 13 metal bond formation

AU - Steinke, Tobias

AU - Gemel, Christian

AU - Cokoja, Mirza

AU - Winter, Manuela

AU - Fischer, Roland A.

PY - 2003

Y1 - 2003

N2 - Insertion of the carbenoid group 13 metal species InCp*(Cp* = pentamethylcyclopentadienyl) and InC(SiMe3)3 into the Rh–Cl bonds of ‘(RhCp*Cl2)2’ yields the new complexes ‘Cp*Rh(InCp*)3(Cl)2’ 1 and ‘Cp*Rh(μ2-Cl)2(InC(SiMe3)3)3’ 2, respectively, exhibiting novel cage-like intermetallic complexes with In–Cl–In bridges.

AB - Insertion of the carbenoid group 13 metal species InCp*(Cp* = pentamethylcyclopentadienyl) and InC(SiMe3)3 into the Rh–Cl bonds of ‘(RhCp*Cl2)2’ yields the new complexes ‘Cp*Rh(InCp*)3(Cl)2’ 1 and ‘Cp*Rh(μ2-Cl)2(InC(SiMe3)3)3’ 2, respectively, exhibiting novel cage-like intermetallic complexes with In–Cl–In bridges.

UR - http://www.scopus.com/inward/record.url?scp=0038731182&partnerID=8YFLogxK

U2 - 10.1039/b301928d

DO - 10.1039/b301928d

M3 - Article

AN - SCOPUS:0038731182

SN - 1359-7345

VL - 3

SP - 1066

EP - 1067

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Insertion of organoindium carbenoids into rhodium halide bonds: Revisiting a classic type of transition metal–group 13 metal bond formation

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