TY - JOUR
T1 - Infrared identification of the FCS radical in an argon matrix
AU - Caspary, Nico
AU - Wurfel, Brent E.
AU - Thoma, Anton
AU - Schallmoser, Günter
AU - Bondybey, Vladimir E.
N1 - Funding Information:
This investigation was supported in part by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.
PY - 1993/9/10
Y1 - 1993/9/10
N2 - The FCS radical has been produced using a pulsed-jet DC discharge technique with several precursor molecules and characterized by IR absorption spectroscopy in an argon matrix. The spectra were analyzed and the following vibrational assignments, confirmed by isotopic studies, and by normal coordinate analysis were determined: ν1 = 1297.9 cm-1, 2ν2 = 910.3 cm-1 in Fermi resonance with ν3 = 917.9 cm-1, and ν1 + ν3 = 2202.6 cm-1 in Fermi resonance with 2ν2 + ν3 = 2195.7 cm-1.
AB - The FCS radical has been produced using a pulsed-jet DC discharge technique with several precursor molecules and characterized by IR absorption spectroscopy in an argon matrix. The spectra were analyzed and the following vibrational assignments, confirmed by isotopic studies, and by normal coordinate analysis were determined: ν1 = 1297.9 cm-1, 2ν2 = 910.3 cm-1 in Fermi resonance with ν3 = 917.9 cm-1, and ν1 + ν3 = 2202.6 cm-1 in Fermi resonance with 2ν2 + ν3 = 2195.7 cm-1.
UR - https://www.scopus.com/pages/publications/43949167864
U2 - 10.1016/0009-2614(93)89334-E
DO - 10.1016/0009-2614(93)89334-E
M3 - Article
AN - SCOPUS:43949167864
SN - 0009-2614
VL - 212
SP - 329
EP - 339
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 3-4
ER -