Influence of the redox active ligand on the reactivity and electronic structure of a series of Fe(TIM) complexes

Keyphrases

• Electronic Structure 100%
• Redox-active Ligands 100%
• TIM-2 100%
• TIM Complex 100%
• Fe(II) 60%
• Density Functional Theory 40%
• Diimine 40%
• Macrocyclic Ligands 40%
• Fe(III) 40%
• Metal Complexes 20%
• Binuclear 20%
• Mssbauer 20%
• Oxidation State 20%
• Low-valent 20%
• Density Functional Calculations 20%
• Acetonitrile 20%
• Macrocycles 20%
• Diimine Ligands 20%
• Fe(II) Complex 20%
• Computational Analysis 20%
• Electron Paramagnetic Resonance 20%
• Computational Data 20%
• Spectral Data 20%
• Synthetic Compounds 20%
• Phosphite 20%
• Redox Properties 20%
• Central Metal Ion 20%
• Dimeric Complex 20%
• Bridged Complexes 20%
• Zn(II) Complex 20%
• Monomeric Complex 20%
• TIM-1 20%
• Preferential Reduction 20%
• Electronic Spectral 20%
• Spectroscopic Techniques 20%
• Redox Series 20%

Chemistry

• Density Functional Theory 100%
• Electronic State 100%
• Macrocyclic Ligand 66%
• Metal Ion 33%
• Iron Complex 33%
• Macrocycle 33%
• EPR Spectroscopy 33%
• Spectroscopy 33%