Influence of a neighbouring Cu centre on electro- and photocatalytic CO2 reduction by Fe-Mabiq

Kerstin Rickmeyer; Matthias Huber; Corinna R. Hess

doi:10.1039/d3cc04777f

Influence of a neighbouring Cu centre on electro- and photocatalytic CO₂ reduction by Fe-Mabiq

Kerstin Rickmeyer, Matthias Huber, Corinna R. Hess

Assistant Professorship of Bioinorganic Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Electrocatalytic and photocatalytic CO₂ reduction by a heterobimetallic Cu/Fe-Mabiq complex were examined and compared to the monometallic [Fe(Mabiq)]⁺. The neighbouring Cu-Xantphos unit leads to marked changes in the electrocatalytic mechanism and enhanced photocatalytic performance.

Original language	English
Pages (from-to)	819-822
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	7
DOIs	https://doi.org/10.1039/d3cc04777f
State	Published - 14 Dec 2023

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title = "Influence of a neighbouring Cu centre on electro- and photocatalytic CO2 reduction by Fe-Mabiq",

abstract = "Electrocatalytic and photocatalytic CO2 reduction by a heterobimetallic Cu/Fe-Mabiq complex were examined and compared to the monometallic [Fe(Mabiq)]+. The neighbouring Cu-Xantphos unit leads to marked changes in the electrocatalytic mechanism and enhanced photocatalytic performance.",

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AU - Rickmeyer, Kerstin

AU - Huber, Matthias

AU - Hess, Corinna R.

PY - 2023/12/14

Y1 - 2023/12/14

N2 - Electrocatalytic and photocatalytic CO2 reduction by a heterobimetallic Cu/Fe-Mabiq complex were examined and compared to the monometallic [Fe(Mabiq)]+. The neighbouring Cu-Xantphos unit leads to marked changes in the electrocatalytic mechanism and enhanced photocatalytic performance.

AB - Electrocatalytic and photocatalytic CO2 reduction by a heterobimetallic Cu/Fe-Mabiq complex were examined and compared to the monometallic [Fe(Mabiq)]+. The neighbouring Cu-Xantphos unit leads to marked changes in the electrocatalytic mechanism and enhanced photocatalytic performance.

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U2 - 10.1039/d3cc04777f

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M3 - Article

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AN - SCOPUS:85180582833

SN - 1359-7345

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SP - 819

EP - 822

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

Influence of a neighbouring Cu centre on electro- and photocatalytic CO₂ reduction by Fe-Mabiq

Abstract

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