In further pursuit of the carbene analogy: Preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

Eva Susanne Schmidt; Annette Schier; Hubert Schmidbaur

doi:10.1039/b101016f

In further pursuit of the carbene analogy: Preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

Eva Susanne Schmidt
, Annette Schier
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Reduction of cis-ethene-1,2-di(tert-butylamido)-gallium(III) chloride with metallic potassium in the presence of N,N,N′,N′- tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations η⁵-coordinated to the pseudocarbene ring system of one monomer and η¹-bonded to the gallium atom of the other.

Original language	English
Pages (from-to)	753-757
Number of pages	5
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/b101016f
State	Published - 2001

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title = "In further pursuit of the carbene analogy: Preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)",

abstract = "Reduction of cis-ethene-1,2-di(tert-butylamido)-gallium(III) chloride with metallic potassium in the presence of N,N,N′,N′- tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations η5-coordinated to the pseudocarbene ring system of one monomer and η1-bonded to the gallium atom of the other.",

author = "Schmidt, \{Eva Susanne\} and Annette Schier and Hubert Schmidbaur",

year = "2001",

doi = "10.1039/b101016f",

language = "English",

pages = "753--757",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "5",

}

In further pursuit of the carbene analogy: Preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I). / Schmidt, Eva Susanne; Schier, Annette; Schmidbaur, Hubert.
In: Journal of the Chemical Society. Dalton Transactions, No. 5, 2001, p. 753-757.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - In further pursuit of the carbene analogy

T2 - Preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

AU - Schmidt, Eva Susanne

AU - Schier, Annette

AU - Schmidbaur, Hubert

PY - 2001

Y1 - 2001

N2 - Reduction of cis-ethene-1,2-di(tert-butylamido)-gallium(III) chloride with metallic potassium in the presence of N,N,N′,N′- tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations η5-coordinated to the pseudocarbene ring system of one monomer and η1-bonded to the gallium atom of the other.

AB - Reduction of cis-ethene-1,2-di(tert-butylamido)-gallium(III) chloride with metallic potassium in the presence of N,N,N′,N′- tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations η5-coordinated to the pseudocarbene ring system of one monomer and η1-bonded to the gallium atom of the other.

UR - https://www.scopus.com/pages/publications/52549087078

U2 - 10.1039/b101016f

DO - 10.1039/b101016f

M3 - Article

AN - SCOPUS:52549087078

SN - 1470-479X

SP - 753

EP - 757

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 5

ER -

In further pursuit of the carbene analogy: Preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

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