TY - JOUR
T1 - In further pursuit of the carbene analogy
T2 - Preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)
AU - Schmidt, Eva Susanne
AU - Schier, Annette
AU - Schmidbaur, Hubert
PY - 2001
Y1 - 2001
N2 - Reduction of cis-ethene-1,2-di(tert-butylamido)-gallium(III) chloride with metallic potassium in the presence of N,N,N′,N′- tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations η5-coordinated to the pseudocarbene ring system of one monomer and η1-bonded to the gallium atom of the other.
AB - Reduction of cis-ethene-1,2-di(tert-butylamido)-gallium(III) chloride with metallic potassium in the presence of N,N,N′,N′- tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations η5-coordinated to the pseudocarbene ring system of one monomer and η1-bonded to the gallium atom of the other.
UR - http://www.scopus.com/inward/record.url?scp=52549087078&partnerID=8YFLogxK
U2 - 10.1039/b101016f
DO - 10.1039/b101016f
M3 - Article
AN - SCOPUS:52549087078
SN - 1470-479X
SP - 753
EP - 757
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 5
ER -