In further pursuit of the carbene analogy: Preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

Eva Susanne Schmidt, Annette Schier, Hubert Schmidbaur

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Abstract

The preparation and crystal structures of (N,N,N′,N′-tetramethylenediamine)potassium[cis-ethene-1,2-di (tert-butylamido)]gallate(I) were discussed. The structure of the compound consisted of dimeric structure with the potassium cations η5-coordinated to the pseudocarbene ring system of one monomer and η1-bonded to the gallium atom of the other. The analysis showed that the line connecting the Ga and K atoms formed an angle of 20.8° with the C2N2Ga ring plane.

Original languageEnglish
Pages (from-to)505-507
Number of pages3
JournalJournal of the Chemical Society. Dalton Transactions
Issue number5
DOIs
StatePublished - 7 Mar 2001
Externally publishedYes

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