Identification, structure, and vibrational assignment of the NO dimer cation

Andreas Strobel; Nils Knoblauch; Jürgen Agreiter; Alice M. Smith; Gereon Niedner-Schatteburg; Vladimir E. Bondybey

doi:10.1021/j100003a006

Identification, structure, and vibrational assignment of the NO dimer cation

Andreas Strobel, Nils Knoblauch, Jürgen Agreiter, Alice M. Smith, Gereon Niedner-Schatteburg, Vladimir E. Bondybey

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Technical University of Munich

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Abstract

We have reinvestigated the NO dimer cation, (NO)₂⁺, both in the gas phase by high-resolution zero kinetic energy-pulsed field ionization (ZEKE-PFI) photoelectron spectroscopy and by infrared absorption spectroscopy in a solid neon matrix. Comparison of the results leads to the conclusion that the matrix infrared absorption bands previously assigned to the anion are actually due to the NO dimer cation. This reassignment also implies that the cation has a centrosymmetric trans structure.

Original language	English
Pages (from-to)	872-874
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	99
Issue number	3
DOIs	https://doi.org/10.1021/j100003a006
State	Published - 1995

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abstract = "We have reinvestigated the NO dimer cation, (NO)2+, both in the gas phase by high-resolution zero kinetic energy-pulsed field ionization (ZEKE-PFI) photoelectron spectroscopy and by infrared absorption spectroscopy in a solid neon matrix. Comparison of the results leads to the conclusion that the matrix infrared absorption bands previously assigned to the anion are actually due to the NO dimer cation. This reassignment also implies that the cation has a centrosymmetric trans structure.",

author = "Andreas Strobel and Nils Knoblauch and J{\"u}rgen Agreiter and Smith, {Alice M.} and Gereon Niedner-Schatteburg and Bondybey, {Vladimir E.}",

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T1 - Identification, structure, and vibrational assignment of the NO dimer cation

AU - Strobel, Andreas

AU - Knoblauch, Nils

AU - Agreiter, Jürgen

AU - Smith, Alice M.

AU - Niedner-Schatteburg, Gereon

AU - Bondybey, Vladimir E.

PY - 1995

Y1 - 1995

N2 - We have reinvestigated the NO dimer cation, (NO)2+, both in the gas phase by high-resolution zero kinetic energy-pulsed field ionization (ZEKE-PFI) photoelectron spectroscopy and by infrared absorption spectroscopy in a solid neon matrix. Comparison of the results leads to the conclusion that the matrix infrared absorption bands previously assigned to the anion are actually due to the NO dimer cation. This reassignment also implies that the cation has a centrosymmetric trans structure.

AB - We have reinvestigated the NO dimer cation, (NO)2+, both in the gas phase by high-resolution zero kinetic energy-pulsed field ionization (ZEKE-PFI) photoelectron spectroscopy and by infrared absorption spectroscopy in a solid neon matrix. Comparison of the results leads to the conclusion that the matrix infrared absorption bands previously assigned to the anion are actually due to the NO dimer cation. This reassignment also implies that the cation has a centrosymmetric trans structure.

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U2 - 10.1021/j100003a006

DO - 10.1021/j100003a006

M3 - Article

AN - SCOPUS:0000783978

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VL - 99

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JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 3

ER -

Identification, structure, and vibrational assignment of the NO dimer cation

Abstract

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