"Hypervalent" Molecules - Low-Valency Candidates for Materials?

Hans H. Karsch, Thomas Segmüller

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

1 Scopus citations

Abstract

A series of silicon and germanium compounds with amidinate ligands havebeen synthesized and investigated spectroscopically and structurally. In contrast tosilicon, germanium also forms stable compounds with amidinate ligands in the +2valence state with remarkable stuctural features.

Original languageEnglish
Title of host publicationOrganosilicon Chemistry Set
Subtitle of host publicationFrom Molecules to Materials
Publisherwiley
Pages194-284
Number of pages91
ISBN (Electronic)9783527620777
ISBN (Print)9783527323470
DOIs
StatePublished - 10 Jun 2008

Keywords

  • Germanium amidinates
  • Hypervalency
  • Low-valency
  • Silicon amidinates

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