Hypercoordinate phosphorus in gold clusters: Novel species [P(AuL) 6]3+(BF4-)3

Edgar Zeller; Hubert Schmidbaur

doi:10.1039/C39930000069

Hypercoordinate phosphorus in gold clusters: Novel species [P(AuL) ₆]³⁺(BF₄^-)₃

Edgar Zeller
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

Treatment of (Me₃Si)₃P with a solution of six equivalents of a (triorganophosphine)gold(I) tetrafluoroborate LAu ⁺BF₄^- (L = Bu^t₃P, Pr ⁱ₃P) in tetrahydrofuran, in the presence of an excess of KF, leads to high yields of the title compounds 1a, b as stable microcrystalline solids; the products, which contain interstitial six-coordinate phosphorus, have been characterized by a detailed NMR study and on the basis of elemental and mass spectrometric analysis.

Original language	English
Pages (from-to)	69-70
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39930000069
State	Published - 1993

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title = "Hypercoordinate phosphorus in gold clusters: Novel species [P(AuL) 6]3+(BF4-)3",

abstract = "Treatment of (Me3Si)3P with a solution of six equivalents of a (triorganophosphine)gold(I) tetrafluoroborate LAu +BF4- (L = But3P, Pr i3P) in tetrahydrofuran, in the presence of an excess of KF, leads to high yields of the title compounds 1a, b as stable microcrystalline solids; the products, which contain interstitial six-coordinate phosphorus, have been characterized by a detailed NMR study and on the basis of elemental and mass spectrometric analysis.",

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T2 - Novel species [P(AuL) 6]3+(BF4-)3

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AU - Schmidbaur, Hubert

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N2 - Treatment of (Me3Si)3P with a solution of six equivalents of a (triorganophosphine)gold(I) tetrafluoroborate LAu +BF4- (L = But3P, Pr i3P) in tetrahydrofuran, in the presence of an excess of KF, leads to high yields of the title compounds 1a, b as stable microcrystalline solids; the products, which contain interstitial six-coordinate phosphorus, have been characterized by a detailed NMR study and on the basis of elemental and mass spectrometric analysis.

AB - Treatment of (Me3Si)3P with a solution of six equivalents of a (triorganophosphine)gold(I) tetrafluoroborate LAu +BF4- (L = But3P, Pr i3P) in tetrahydrofuran, in the presence of an excess of KF, leads to high yields of the title compounds 1a, b as stable microcrystalline solids; the products, which contain interstitial six-coordinate phosphorus, have been characterized by a detailed NMR study and on the basis of elemental and mass spectrometric analysis.

UR - https://www.scopus.com/pages/publications/0011971827

U2 - 10.1039/C39930000069

DO - 10.1039/C39930000069

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JF - Journal of the Chemical Society, Chemical Communications

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ER -

Hypercoordinate phosphorus in gold clusters: Novel species [P(AuL) ₆]³⁺(BF₄^-)₃

Abstract

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