TY - JOUR
T1 - Hypercoordinate phosphorus in gold clusters
T2 - Novel species [P(AuL) 6]3+(BF4-)3
AU - Zeller, Edgar
AU - Schmidbaur, Hubert
PY - 1993
Y1 - 1993
N2 - Treatment of (Me3Si)3P with a solution of six equivalents of a (triorganophosphine)gold(I) tetrafluoroborate LAu +BF4- (L = But3P, Pr i3P) in tetrahydrofuran, in the presence of an excess of KF, leads to high yields of the title compounds 1a, b as stable microcrystalline solids; the products, which contain interstitial six-coordinate phosphorus, have been characterized by a detailed NMR study and on the basis of elemental and mass spectrometric analysis.
AB - Treatment of (Me3Si)3P with a solution of six equivalents of a (triorganophosphine)gold(I) tetrafluoroborate LAu +BF4- (L = But3P, Pr i3P) in tetrahydrofuran, in the presence of an excess of KF, leads to high yields of the title compounds 1a, b as stable microcrystalline solids; the products, which contain interstitial six-coordinate phosphorus, have been characterized by a detailed NMR study and on the basis of elemental and mass spectrometric analysis.
UR - http://www.scopus.com/inward/record.url?scp=0011971827&partnerID=8YFLogxK
U2 - 10.1039/C39930000069
DO - 10.1039/C39930000069
M3 - Article
AN - SCOPUS:0011971827
SN - 0022-4936
SP - 69
EP - 70
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 1
ER -