TY - JOUR
T1 - Hydrolysis to a Complex with a Central, Octahedral (μ6‐O)In6 Unit
AU - Hegetschweiler, Kaspar
AU - Ghisletta, Michele
AU - Fässler, Thomas F.
AU - Nesper, Reinhard
PY - 1993/10
Y1 - 1993/10
N2 - Hitherto unknown for main group elements was the structural element M6O13, which has now been found in the cation 1, taci = 1,3,5‐triamino‐1,3,5‐trideoxyinositol. In the In6O13 core with a μ6‐oxo center and approximate Oh symmetry, the OIn6 unit is completely shielded by the six‐coordinate (taci–3 H) ligands, which explains the surprising stability of 1 toward further hydrolysis. (Figure Presented.)
AB - Hitherto unknown for main group elements was the structural element M6O13, which has now been found in the cation 1, taci = 1,3,5‐triamino‐1,3,5‐trideoxyinositol. In the In6O13 core with a μ6‐oxo center and approximate Oh symmetry, the OIn6 unit is completely shielded by the six‐coordinate (taci–3 H) ligands, which explains the surprising stability of 1 toward further hydrolysis. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33749110683&partnerID=8YFLogxK
U2 - 10.1002/anie.199314261
DO - 10.1002/anie.199314261
M3 - Article
AN - SCOPUS:33749110683
SN - 0570-0833
VL - 32
SP - 1426
EP - 1428
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 10
ER -