Homogeneous Catalytic Oxidation of Arenes and a New Synthesis of Vitamin K3

Waldemar Adam; Jianhua Lin; Chantu R. Saha‐Möller; Wolfgang A. Herrmann; Richard W. Fischer; João D.G. Correia

doi:10.1002/anie.199424751

Homogeneous Catalytic Oxidation of Arenes and a New Synthesis of Vitamin K₃

Waldemar Adam, Jianhua Lin, Chantu R. Saha‐Möller, Wolfgang A. Herrmann, Richard W. Fischer, João D.G. Correia

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

Methyltrioxorhenium(VII)‐catalyzed oxidation of 2‐methylnaphthalene (1) with hydrogen peroxide leads to vitamin K₃ (2) in good yield and high regioselectivity. The currently employed industrial synthesis of 2 with chromic acid produces 18 kg of chromium‐containing waste per kg of product. (Figure Presented.)

Original language	English
Pages (from-to)	2475-2477
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	23-24
DOIs	https://doi.org/10.1002/anie.199424751
State	Published - 3 Jan 1995

Access to Document

10.1002/anie.199424751

Cite this

@article{ccf4a1d676504de5a21040a8bda1224a,

title = "Homogeneous Catalytic Oxidation of Arenes and a New Synthesis of Vitamin K3",

abstract = "Methyltrioxorhenium(VII)‐catalyzed oxidation of 2‐methylnaphthalene (1) with hydrogen peroxide leads to vitamin K3 (2) in good yield and high regioselectivity. The currently employed industrial synthesis of 2 with chromic acid produces 18 kg of chromium‐containing waste per kg of product. (Figure Presented.)",

author = "Waldemar Adam and Jianhua Lin and Saha‐M{\"o}ller, \{Chantu R.\} and Herrmann, \{Wolfgang A.\} and Fischer, \{Richard W.\} and Correia, \{Jo{\~a}o D.G.\}",

year = "1995",

month = jan,

day = "3",

doi = "10.1002/anie.199424751",

language = "English",

volume = "33",

pages = "2475--2477",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

number = "23-24",

}

TY - JOUR

T1 - Homogeneous Catalytic Oxidation of Arenes and a New Synthesis of Vitamin K3

AU - Adam, Waldemar

AU - Lin, Jianhua

AU - Saha‐Möller, Chantu R.

AU - Herrmann, Wolfgang A.

AU - Fischer, Richard W.

AU - Correia, João D.G.

PY - 1995/1/3

Y1 - 1995/1/3

N2 - Methyltrioxorhenium(VII)‐catalyzed oxidation of 2‐methylnaphthalene (1) with hydrogen peroxide leads to vitamin K3 (2) in good yield and high regioselectivity. The currently employed industrial synthesis of 2 with chromic acid produces 18 kg of chromium‐containing waste per kg of product. (Figure Presented.)

AB - Methyltrioxorhenium(VII)‐catalyzed oxidation of 2‐methylnaphthalene (1) with hydrogen peroxide leads to vitamin K3 (2) in good yield and high regioselectivity. The currently employed industrial synthesis of 2 with chromic acid produces 18 kg of chromium‐containing waste per kg of product. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33745166774

U2 - 10.1002/anie.199424751

DO - 10.1002/anie.199424751

M3 - Article

AN - SCOPUS:33745166774

SN - 0570-0833

VL - 33

SP - 2475

EP - 2477

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 23-24

ER -

Homogeneous Catalytic Oxidation of Arenes and a New Synthesis of Vitamin K₃

Abstract

Access to Document

Other files and links

Fingerprint

Cite this