Homogeneous Catalysis by Manganese-Based Pincer Complexes

Marcel Garbe, Kathrin Junge, Matthias Beller

Research output: Contribution to journalReview articlepeer-review

276 Scopus citations

Abstract

Base-metal catalysis, especially with non-noble-metal pincer-type catalysts, is increasingly used in organic synthesis and thus becoming more and more important for organometallic chemistry. After ruthenium-, iridium- and iron-based pincer-type complexes became established as state-of-the-art catalysts for (de)hydrogenation reactions in the past decade, manganese complexes have most recently been successfully applied in related transformations. Specifically, this microreview covers their recent progress in (de)hydrogenation and transfer (de)hydrogenation as well as in C–C and C–X bond-forming reactions.

Original languageEnglish
Pages (from-to)4344-4362
Number of pages19
JournalEuropean Journal of Organic Chemistry
Volume2017
Issue number30
DOIs
StatePublished - 17 Aug 2017
Externally publishedYes

Keywords

  • Bond formation
  • Dehydrogenation
  • Earth-abundant metals
  • Hydrogenation
  • Manganese
  • Pincer complex
  • Transfer hydrogenation

Fingerprint

Dive into the research topics of 'Homogeneous Catalysis by Manganese-Based Pincer Complexes'. Together they form a unique fingerprint.

Cite this