Highly regioselective osmium-catalyzed hydroformylation

Lipeng Wu, Qiang Liu, Anke Spannenberg, Ralf Jackstell, Matthias Beller

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

The first highly regioselective and general osmium-catalyzed hydroformylation of olefins to aldehydes is reported. The combination of Os3(CO)12 and imidazoyl-substituted phosphine ligands allows n-selective (up to 99%) hydroformylation of bulk aliphatic as well as functional alkenes in good yields (64-87%).

Original languageEnglish
Pages (from-to)3080-3082
Number of pages3
JournalChemical Communications
Volume51
Issue number15
DOIs
StatePublished - 21 Feb 2015
Externally publishedYes

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