High phosphine coordination numbers of the lanthanoids: σ- and π-type coordination in [Sm{CH(PMe2)2}3] 2

Hans H. Karsch; G. Ferazin; P. Bissinger

doi:10.1039/C39940000505

High phosphine coordination numbers of the lanthanoids: σ- and π-type coordination in [Sm{CH(PMe₂)₂}₃] ₂

Hans H. Karsch, G. Ferazin, P. Bissinger

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The dimeric title complex, obtained from [Sm(O₃SCF ₃)₃] and [LiCH(PMe₂)₂], contains four π-type and two bridging σ-type coordinated ligands.

Original language	English
Pages (from-to)	505-506
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39940000505
State	Published - 1994

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title = "High phosphine coordination numbers of the lanthanoids: σ- and π-type coordination in [Sm\{CH(PMe2)2\}3] 2",

abstract = "The dimeric title complex, obtained from [Sm(O3SCF 3)3] and [LiCH(PMe2)2], contains four π-type and two bridging σ-type coordinated ligands.",

author = "Karsch, \{Hans H.\} and G. Ferazin and P. Bissinger",

year = "1994",

doi = "10.1039/C39940000505",

language = "English",

pages = "505--506",

journal = "Journal of the Chemical Society, Chemical Communications",

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publisher = "Chemical Society",

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T1 - High phosphine coordination numbers of the lanthanoids

T2 - σ- and π-type coordination in [Sm{CH(PMe2)2}3] 2

AU - Karsch, Hans H.

AU - Ferazin, G.

AU - Bissinger, P.

PY - 1994

Y1 - 1994

N2 - The dimeric title complex, obtained from [Sm(O3SCF 3)3] and [LiCH(PMe2)2], contains four π-type and two bridging σ-type coordinated ligands.

AB - The dimeric title complex, obtained from [Sm(O3SCF 3)3] and [LiCH(PMe2)2], contains four π-type and two bridging σ-type coordinated ligands.

UR - https://www.scopus.com/pages/publications/0010704712

U2 - 10.1039/C39940000505

DO - 10.1039/C39940000505

M3 - Article

AN - SCOPUS:0010704712

SN - 0022-4936

SP - 505

EP - 506

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 4

ER -

High phosphine coordination numbers of the lanthanoids: σ- and π-type coordination in [Sm{CH(PMe₂)₂}₃] ₂

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