TY - JOUR
T1 - Hexahydrido(pentamethylcyclopentadienyl)rhenium, [(C5Me5)ReH6]
AU - Herrmann, Wolfgang A.
AU - Okuda, Jun
PY - 1986/12
Y1 - 1986/12
N2 - The novel organometallic polyhydride 2, formally a ReVII derivative, is surprisingly formed upon reaction of the ReV complex 1 with LiAlH4 followed by careful methanolysis. Complex 2 has a fluxional structure at room temperature; at lower temperatures, the complex has a rigid, pentagonal‐bipyramidal geometry. (Figure Presented.)
AB - The novel organometallic polyhydride 2, formally a ReVII derivative, is surprisingly formed upon reaction of the ReV complex 1 with LiAlH4 followed by careful methanolysis. Complex 2 has a fluxional structure at room temperature; at lower temperatures, the complex has a rigid, pentagonal‐bipyramidal geometry. (Figure Presented.)
UR - https://www.scopus.com/pages/publications/84985560898
U2 - 10.1002/anie.198610921
DO - 10.1002/anie.198610921
M3 - Article
AN - SCOPUS:84985560898
SN - 0570-0833
VL - 25
SP - 1092
EP - 1093
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 12
ER -