Heterolysis of Re2O7: Generation and Stabilization of the Cation [ReO3]+

Wolfgang A. Herrmann; Peter W. Roesky; Fritz E. Kühn; Wolfgang Scherer; Matthias Kleine

doi:10.1002/anie.199317141

Heterolysis of Re₂O₇: Generation and Stabilization of the Cation [ReO₃]⁺

Wolfgang A. Herrmann
, Peter W. Roesky
, Fritz E. Kühn
, Wolfgang Scherer
, Matthias Kleine

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

No side products and no change in the oxidation state of the metal are observed in the cleavage of Re₂O₇ into [ReO₃]⁺ and [ReO₄]⁻, if the cation is generated and stabilized by open‐chain or cyclic tridentate donor ligands (XNH, NCH₃, S in 1). The heterolysis, which is driven by coordination chemistry factors, is set up by an unsymmetric solvation of Re₂O₇ in donor solvents like THE. (Figure Presented.)

Original language	English
Pages (from-to)	1714-1716
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	32
Issue number	12
DOIs	https://doi.org/10.1002/anie.199317141
State	Published - Dec 1993

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title = "Heterolysis of Re2O7: Generation and Stabilization of the Cation [ReO3]+",

abstract = "No side products and no change in the oxidation state of the metal are observed in the cleavage of Re2O7 into [ReO3]+ and [ReO4]−, if the cation is generated and stabilized by open‐chain or cyclic tridentate donor ligands (XNH, NCH3, S in 1). The heterolysis, which is driven by coordination chemistry factors, is set up by an unsymmetric solvation of Re2O7 in donor solvents like THE. (Figure Presented.)",

author = "Herrmann, \{Wolfgang A.\} and Roesky, \{Peter W.\} and K{\"u}hn, \{Fritz E.\} and Wolfgang Scherer and Matthias Kleine",

year = "1993",

month = dec,

doi = "10.1002/anie.199317141",

language = "English",

volume = "32",

pages = "1714--1716",

journal = "Angewandte Chemie International Edition in English",

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T1 - Heterolysis of Re2O7

T2 - Generation and Stabilization of the Cation [ReO3]+

AU - Herrmann, Wolfgang A.

AU - Roesky, Peter W.

AU - Kühn, Fritz E.

AU - Scherer, Wolfgang

AU - Kleine, Matthias

PY - 1993/12

Y1 - 1993/12

N2 - No side products and no change in the oxidation state of the metal are observed in the cleavage of Re2O7 into [ReO3]+ and [ReO4]−, if the cation is generated and stabilized by open‐chain or cyclic tridentate donor ligands (XNH, NCH3, S in 1). The heterolysis, which is driven by coordination chemistry factors, is set up by an unsymmetric solvation of Re2O7 in donor solvents like THE. (Figure Presented.)

AB - No side products and no change in the oxidation state of the metal are observed in the cleavage of Re2O7 into [ReO3]+ and [ReO4]−, if the cation is generated and stabilized by open‐chain or cyclic tridentate donor ligands (XNH, NCH3, S in 1). The heterolysis, which is driven by coordination chemistry factors, is set up by an unsymmetric solvation of Re2O7 in donor solvents like THE. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33748234284

U2 - 10.1002/anie.199317141

DO - 10.1002/anie.199317141

M3 - Article

AN - SCOPUS:33748234284

SN - 0570-0833

VL - 32

SP - 1714

EP - 1716

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 12

ER -

Heterolysis of Re₂O₇: Generation and Stabilization of the Cation [ReO₃]⁺

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